期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 16, 页码 3253-3257出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob07049a
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资金
- CNRS
- Universite de Strasbourg
- MRT
Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (eta(2)-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly fused unsaturated tricyclic lactones which represent relevant substructures of numerous bioactive compounds.
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