期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 34, 页码 6987-6994出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25622c
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资金
- CSIR New Delhi
- UGC New Delhi
- DST, New Delhi [SR/S1/OC-44/2009]
An efficient high yielding improved method for the enantio- and diastereoselective cyclopropanation of chiral epoxides using triethylphosphonoacetate and base (Wadsworth-Emmons cyclopropanation) is reported. The utility of this protocol is illustrated by concise and practical synthesis of cascarillic acid, grenadamide and L-(-)-CCG-II, a cyclopropane containing natural products.
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