期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 34, 页码 6817-6825出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25650a
关键词
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资金
- National Natural Science Foundation of China [21025206, 20832003, 20972118]
- MOST of China [2011CB808600]
- Fundamental Research Funds for the Central Universities
- Program for New Century Excellent Talents in University (NCET)
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
- Academic Award for Excellent Ph.D. Candidates
- Ministry of Education of China
The Negishi coupling has been widely applied in organic synthesis, while relevant mechanistic studies are relatively rare. To obtain an understanding of the fundamental steps in the Negishi coupling, oxidative addition, transmetalation and reductive elimination, the kinetic investigation has served as one of the most important strategies. In this review, insights into the elementary steps in the Negishi coupling through kinetic investigations are summarized.
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