4.6 Article

Nickel-catalyzed C-P coupling of aryl mesylates and tosylates with H(O)PR1R2

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 17, 页码 3500-3505

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25225b

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  1. Nippon Chemical Industrial Co., Ltd
  2. National Natural Science Foundation of China [20972095]
  3. Science and Technology Commission of Shanghai Municipality [09JC1407800]

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A method was developed for the nickel-catalyzed phosphonylation of aryl mesylates and tosylates with H (O)(PRR2)-R-1. To the best of our knowledge, this is the first example of nickel-catalyzed C-P coupling of aryl mesylates and tosylates. Most of the substrates gave moderate to good yields under our catalytic system.

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