期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 46, 页码 9134-9136出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob26674a
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资金
- Florida Department of Health [07KN-12]
- National Science Foundation [CHE-1152850, CHE-0946858]
- Division Of Chemistry [0946858] Funding Source: National Science Foundation
The periselective Diels-Alder reaction of 5-substituted penta-methylcyclopentadienes and nitroethylene has been realized by helical-chiral hydrogen bond donor catalysts. To our knowledge, this represents the first asymmetric catalytic nitroalkene Diels-Alder reaction via activation of nitroalkene, and thus establishes its proof-of-principle.
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