期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 10, 期 18, 页码 3715-3720出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ob25425e
关键词
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资金
- National Natural Science Foundation of China [21176039, 20876021, 20923006]
- Education Department of Liaoning Province [2009S021]
In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)(2)center dot 4H(2)O as catalyst, TBHP as oxidant and acid as the additive. Avariety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.
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