期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 1, 页码 36-51出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00610f
关键词
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资金
- Netherlands Organization for Scientific Research (NWO-CW) [700.54.654]
- DSM [700.54.654]
- Schering-Plough [700.54.654]
The literature on enantioselective liquid-liquid extraction (ELLE) spans more than half a century of research. Nonetheless, a comprehensive overview has not appeared during the past few decades. Enantioselective liquid-liquid extraction is a technology of interest for a wide range of chemists and chemical engineers in the fields of fine chemicals, pharmaceuticals, agrochemicals, fragrances and foods. In this review the principles and advances of resolution through enantioselective liquid-liquid extraction are discussed, starting with an introduction on the principles of enantioselective liquid-liquid extraction including host-guest chemistry, extraction and phase transfer mechanisms, and multistage liquid-liquid extraction processing. Then the literature on enantioselective liquid-liquid extraction systems is reviewed, structured on extractant classes. The following extractant classes are considered: crown ether based extractants, metal complexes and metalloids, extractants based on tartrates, and a final section with all other types of chiral extractants.
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