期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 9, 页码 3146-3150出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob05113j
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资金
- Deutscher Akademischer Austauschdienst (DAAD)
Titanium chelate addition of aryl nucleophiles to cyclopropyl aldehyde 6 followed by a tin-catalyzed one-pot retro-aldol, acetalisation and lactonisation sequence afforded cis and trans gamma-aryllactone acetals. A gamma-furyllactone derived by this approach was further transformed in two steps to model compounds for the oxidised northeastern sectors of selected Pseudopterogorgia diterpenoids.
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