期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 5, 页码 1407-1418出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ob00818d
关键词
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The 1,2-sulfone rearrangement resulting from nucleophilic addition to bis activated vinyl-sulfones has been studied in more detail. Various nucleophiles activated by different types of catalysts (enamine, Bronsted base, thiourea) are able to promote such rearrangement in excellent yields and moderate to excellent enantioselectivities (up to 94% ee). Mechanistic studies have led to a better understanding of the mechanism and allowed its application to other electrophiles such as vinyl-sulfone acrylates.
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