期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 9, 期 22, 页码 7913-7920出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ob06128c
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资金
- DST, New Delhi, India [SR/SI/OC-12/2007]
- CSIR (New Delhi)
A simple and practical procedure for the synthesis of aza- and oxacycles, which possess an array of stereogenic functionalities, is described. This protocol relies on tandem Cu-catalyzed coupling of suitably functionalized terminal alkyne with diazoester followed by isomerization and subsequent aza or oxa-Michael reaction, thus generating the required scaffold with high diastereoselectivity.
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