☆ 4.6 Article

Modification at a boron unit: tuning electronic and optical properties of π-conjugated acyclic anion receptors

ORGANIC & BIOMOLECULAR CHEMISTRY (2010)

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY

卷 8, 期 19, 页码 4308-4315

出版社

ROYAL SOC CHEMISTRY

DOI: 10.1039/c0ob00044b

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Chemistry, Organic

资金

Ministry of Education, Culture, Sports, Science and Technology (MEXT) [21750155, 19022036]
Ritsumeikan Global Innovation Research Organization (R-GIRO) [2008-2013]
Grants-in-Aid for Scientific Research [19022036] Funding Source: KAKEN

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摘要

Substituents at the boron unit of dipyrrolyldiketone boron complexes as it-conjugated acyclic anion receptors play crucial roles for the tuning of solid-state molecular assemblies, anion-binding behaviour and electronic and optical properties. In particular, emission quantum yields can be significantly tunable by boron substituents and pyrrole alpha-aryl moieties.

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