期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 8, 期 1, 页码 107-113出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b918179b
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资金
- Education Commission Pakistan
- Chinese Government Scholarship Programme 2007-2009
Structural revision of lawsonicin, a natural product of Lawsonia alba, is reported based upon comparison of its spectral data with that of the naturally occurring dihydrobenzo[b]furan neolignan (rac)-trans-dihydrodehydrodiconiferyl alcohol, which is found to be identical. A concise synthesis of dihydrodehydrodiconiferyl alcohol, via Rh-2[S-DOSP](4)-catalysed intramolecular C-H insertion, is described.
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