期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 8, 期 14, 页码 3281-3286出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c003943h
关键词
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The novel alpha-amino acid BpAib, a partially conformationally restricted analogue of the currently extensively used 3-(4-benzoylphenyl)alanine (Bpa) photoaffinity label, was synthesized, optically resolved, fully characterized, and appropriately derivatized. An intermolecular photocrosslinking experiment highlighted its regioselective reactivity towards the S-methyl side-chain group of a Met-based dipeptide, which is closely comparable to that of Bpa.
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