期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 7, 期 23, 页码 5028-5033出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b915013g
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资金
- National Science Foundation of China [20872036]
- Shanghai Municipal Education Commission [09ZZ45]
- Science and Technology Commission of Shanghai Municipality [09JC1404900]
Water and ethyl diazoacetate were found to be matched components for generating highly reactive nucleophilic oxonium ylide in the presence of a dirhodium acetate catalyst. Simultaneous trapping of the oxonium ylide intermediate with aryl imines gave beta-aryl isoserine derivatives with high diastereoselectivity.
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