期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 7, 期 18, 页码 3855-3861出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b909248j
关键词
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资金
- National Natural Science Foundation of China
- Ministry of Science and Technology of China
The Heck coupling of aryl iodides with pyranoid glycals using a catalytic amount of Pd(OAc)(2) to form pyranoid aryl C-glycosides has been achieved. The reaction takes place smoothly in the presence of Ag2CO3 and Cu(OAc)(2) (or DMSO) in acetonitrile. This arylation process, which occurs in a highly regio- and stereo-selective manner, provides a simple, mild, and efficient approach to the synthesis of aryl 2-deoxy-C-glycopyranosides.
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