Sun-induced leaf fluorescence was inferred by using high resolution (0.5 cm(-1)) radiance measurements and simulated spectra of the solar irradiance at the ground level, in the region of the O-2-B absorption band. The minimization of a cost function was performed in the Fourier transform domain in order to make an accurate fit of the Instrumental Line-Shape that convoluted the simulated spectrum. Second-order polynomials were used to fit the leaf fluorescence and reflectance in the 100-cm(-1)-wide spectral window. The scale and the instrumental conversion factor were also fitted in order to obtain an accuracy that could not be attained by using the radiance measurements alone. (C) 2008 Optical Society of America.
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