期刊
TETRAHEDRON LETTERS
卷 56, 期 23, 页码 3431-3434出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.01.186
关键词
Metalloradical; Radical; Cobalt; Aziridination; Azide; Porphyrin
资金
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152767, 1624211] Funding Source: National Science Foundation
- NIGMS NIH HHS [R01 GM098777] Funding Source: Medline
Aryloxysulfonyl azides can be effectively activated by commercially available cobalt(II) complex of meso-tetraphenylporphyrin ([Co(TPP)]) at room temperature under neutral and nonoxidative conditions for selective radical aziridination of alkenes via metalloradical catalysis. The [Co(TPP)]-catalyzed radical aziridination system is suitable for different combinations of olefin substrates and aryloxysulfonyl azides, producing various N-aryloxysulfonyl aziridine derivatives in good to excellent yields. In addition to generating the environmentally benign N-2 as the only byproduct, this Co(II)-based metalloradical aziridination process features mild reaction conditions and operational simplicity. (C) 2015 Elsevier Ltd. All rights reserved.
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