期刊
TETRAHEDRON LETTERS
卷 56, 期 2, 页码 312-315出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.11.073
关键词
Iron; Phenanthrene; Atom-efficient; Tandem; Cyclization
资金
- CSIR, New Delhi, India
An iron-catalyzed efficient synthesis of substituted phenanthrenes through tandem intramolecular C-C/C-O bond formations/aromatization of 2'-alkynyl-biphenyl-2-carbinols is reported. This method provides a novel, highly efficient, and straightforward route to 9,10-substituted phenanthrene in good to excellent yields. The present strategy involves tandem Fe(OTf)(3)-catalyzed generation of benzylic carbocation, 6-exo-dig cyclization of alkyne, carbon-oxygen bond formation, and aromatization steps in one pot. (C) 2014 Elsevier Ltd. All rights reserved.
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