期刊
TETRAHEDRON LETTERS
卷 56, 期 43, 页码 5937-5940出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.09.044
关键词
Indole; C-H cyanation; Aerobic oxidation; Copper; DMF
资金
- NSFC [21373080, 21403062]
- HNNSF [2015JJ3039]
- Fundamental Research Funds for the Central Universities (Hunan University)
Under an oxygen atmosphere, the copper-mediated direct C3-cyanation of indole C-H bonds, using cheap and safe DMF as a CN source, took place selectively to produce the corresponding C3-cyanoindoles in good yields. A possible mechanism for this selective cyanation was proposed. (C) 2015 Elsevier Ltd. All rights reserved.
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