期刊
TETRAHEDRON
卷 71, 期 24, 页码 4203-4212出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2015.04.089
关键词
Push-pull compounds; Benzothiadiazole; Pyridine; Carbazole; Phenothiazine
资金
- Department of Science and Technology, New Delhi, India [DST/TSG/PT/2013/09]
- DST through FIST program
New dyes containing pyridine anchoring group and different nitrogen-based heterocyclic electron-donating units linked via benzothiadiazole moiety have been synthesized and characterized by photophysical studies. Incorporation of benzothiadiazole extended the absorption onset into the lower energy region up to 600 nm. The dyes possessing vinyl linker between the heterocyclic donor and benzothiadiazole exhibited red-shifted absorption with high molar extinction coefficient than the dyes, which contain heterocyclic donor directly attached to the benzothiadiazole unit. The dyes exhibited acid-ochromism in the absorption spectra presumably due to the protonation of the pyridine nitrogen. These materials exhibited good thermal stability and their thermal-decomposition temperatures are in the range, 355-407 degrees C. The dye-sensitized solar cells fabricated using a dye containing phenothiazine donor showed power conversion efficiency of 1.97%. Electrochemical impedance studies reveal that the charge separation is highly dependent on the structural composition of the dyes. (C) 2015 Elsevier Ltd. All rights reserved.
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