4.5 Article

Reagent and Catalyst Design for Asymmetric Hypervalent Iodine Oxidations

期刊

SYNTHESIS-STUTTGART
卷 47, 期 5, 页码 587-603

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379892

关键词

hypervalent iodine; asymmetric transformations; homogeneous organocatalysis; oxidations; carbon-carbon bond formations; carbon-heteroatom bond formations

资金

  1. CNRS
  2. Universite Joseph Fourier

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In this review are compiled the different possible transformations using environmentally benign chiral hypervalent iodine reagents and catalysts. Herein is presented an overview of asymmetric oxidation of sulfides to sulfoxides, oxidation of alkenes, -functionalization of carbonyl compounds and dearomatization reactions. 1 Introduction 2 Chiral Hypervalent Iodine Reagents 3 Oxidation of Sulfides to Sulfoxides 4 Oxidation of Alkenes 5 -Functionalization of Carbonyl Compounds 6 Dearomatization Reactions 7 Conclusion

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