期刊
SYNTHESIS-STUTTGART
卷 47, 期 14, 页码 2032-2037出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1380813
关键词
nickel; ketones; arylation; cross coupling; medicinal chemistry
资金
- ERC (Advanced Researcher award-FUNCAT)
- 7th Framework Program [NMP2-LA-2010-246461]
- EPSRC
- King Saud University
- Royal Society
A nickel-catalyzed methodology for the -arylation of ketones has been applied to the synthesis of an industrially relevant intermediate. The optimization of the reaction shows the important influence of subtle changes in reaction conditions, and leads to an improved procedure employing only a small excess of the substrate and a relatively low catalyst loading.
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