期刊
SYNLETT
卷 26, 期 13, 页码 1905-1910出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379930
关键词
acylation; cross-coupling; phosphonic acids; total synthesis; ligands
资金
- National Academy of Science of Ukraine [0112U004502, 0115U003044, 0112U002186]
Several synthetic strategies for the construction of linear and branched oligomesogenic phosphonic acids are examined, which differ in the method of building the key bimesogen unit. An efficient synthetic approach to the most promising compounds employs regioselective Kumada cross-coupling between [11-(4'-pentylbiphenyl-4-yl)undecyl] magnesium bromide and 4-(11-bromoundecyl)-4'-iodobiphenyl as the key step. Preliminary studies on the ability of the new ligands to stabilize nanoparticles colloids in nematic liquid crystals are undertaken for the example of quantum dots.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据