期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 20, 页码 16886-16890出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj03955k
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资金
- National Research Foundation of Korea (NRF) - Korean Government, through the Center for New Directions in Organic Synthesis [NRF-2014R1A5A1011165]
A simple, mild, efficient and chemoselective catalytic method for the straightforward synthesis of an interesting class of 2-aryl/alkyl-substituted-3-diaryl indolyl methanes in high yield is reported. This atom-efficient method proceeds via a gold-catalyzed one-pot sequential intramolecular hydroamination (C-N bond formation) of 2-alkynylanilines followed by a 1,6-conjugate addition to p-quinonemethides. The p-quinonemethides, which contain aldehyde functional groups, preferentially participate in 1,6-conjugate addition, while the aldehyde functional group remains unreactive.
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