Article
Polymer Science
Arielle Mann, Marcus Weck
Summary: This contribution describes the synthesis of a novel unsymmetrical substituted tetraalkoxy[2.2]paracyclophane-1,9-diene and its polymerization to produce copolymers with alternating cis,trans-poly(p-phenylenevinylene)s. The synthesized polymers exhibit unique optical properties.
Article
Chemistry, Applied
Ying-Chen Duan, Ying Gao, Xiao-Xia You, Yong Wu, Yun Geng, Yue-Gang Fu, Zhong-Min Su
Summary: The TADF nature of [2.2]paracyclophane derivatives with spatially conjugated structures was studied, revealing the influence of the conjugated structure on their optical properties. The design of new molecules resulted in potential efficient red-light TADF materials with enhanced radiation rate and decreased internal conversion rate.
Article
Chemistry, Applied
Yibo Li, Yongjun Song, Ke Zhang, Yue Xiu, Pingping Wang, Mingxing Tian, Lei He
Summary: This study reports the development of TSCT-TADF emitters for OLED applications by fixing cyano-substituted fluorenes as acceptors. The emitters exhibit high external quantum efficiencies up to 14.9% and emit blue-green or yellow light. The results demonstrate the promising use of cyano-substituted fluorenes with a planar and rigid geometry as acceptors for developing TSCT-TADF emitters.
Article
Chemistry, Organic
Simon Felder, Marie-Leonie Delcourt, Manon H. E. Bousquet, Denis Jacquemin, Rafael Rodriguez, Ludovic Favereau, Jeanne Crassous, Laurent Micouin, Erica Benedetti
Summary: This study describes the synthesis and photophysical characterization of differently substituted planar chiral analogues of PRODAN based on a [2.2]paracyclophane scaffold. Results show that the (chir)optical properties of the new phane compounds strongly depend on their substitution patterns, with more pronounced solvatochromism and clear chiroptical behaviors observed when the substituents are placed on the two rings of the pCp core in a non-co-planar arrangement (pseudo-para derivative), which may facilitate the design of new pCp-based luminophores with finely tuned photophysical properties.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Bijesh Sekaran, Andrew Dawson, Youngwoo Jang, Kusum V. MohanSingh, Rajneesh Misra, Francis D'Souza
Summary: By utilizing a combination of cycloaddition-retroelectrocyclization reaction, free-base and zinc porphyrins were decorated with strong charge transfer complexes, forming a novel push-pull system. Various techniques were used to investigate the physico-chemical properties of these compounds, highlighting the importance of the nature of porphyrins and the second electron donor in governing the charge transfer events.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Kuan Chen, Yanju Luo, Ming Sun, Chuanhao Liu, Mengjiao Jia, Caixia Fu, Xingsha Shen, Chuan Li, Xujun Zheng, Xuemei Pu, Yan Huang, Zhiyun Lu
Summary: A compound called NIC-DMAC has been developed using the through-space electronic coupling effect. It exhibits a long-lived (CT)-C-3 state at the single-molecule level. Experimental and computational approaches have been used to elucidate its photophysical processes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Applied
Yangyang Huang, Dong-Hai Zhang, Xiao-Dong Tao, Zhuangzhuang Wei, Shanshan Jiang, Lingyi Meng, Ming-Xue Yang, Xu-Lin Chen, Can-Zhong Lu
Summary: Thermally activated delayed fluorescence (TADF) materials with through-space charge transfer (TSCT) have attracted extensive attention recently. In this study, two triptycene-derived TADF molecules with ortho-donor (D)-acceptor (A) conformations were designed and characterized. These emitters exhibited unique V-shaped face-to-face D-A alignments with significant intramolecular D-A interactions, enabling TSCT in addition to throughbond charge transfer (TBCT). The emitters also showed excellent thermal stability and high film-formation quality due to the rigid 3D triptycene scaffold. The doped OLEDs utilizing these emitters achieved high external quantum efficiencies up to 20.5%.
Review
Materials Science, Multidisciplinary
Qin Xue, Guohua Xie
Summary: Charge transfer is crucial in governing exciton dynamics in organic emitters, particularly in thermally activated delayed fluorescence (TADF) emitters. It plays a role in shaping radiative decays of excitons and modulating luminescent properties. Through-space charge transfer is found to be effective in changing emissive colors, exciton lifetimes, and quantum yields in OLEDs.
ADVANCED OPTICAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Sai Luo, Junjie Wang, Nengquan Li, Xiu-Fang Song, Xintong Wan, Kai Li, Chuluo Yang
Summary: This study presents a molecular design using through-space charge transfer (TSCT) states to address the challenges of B- and N-embedded MR-TADF emitters. The introduction of TSCT states enables a higher RISC rate, leading to improved device efficiencies and operational stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Jong-Won Song, Kimihiko Hirao
Summary: In this study, we conducted calculations of intra- and intermolecular charge-transfer excitations in two molecules using different computational methods. The results showed that the alkane chain had minimal effect on the charge-transfer excitation energy, while the conjugated polyene chain reduced the excitation energy through delocalization.
CHEMICAL PHYSICS LETTERS
(2022)
Article
Chemistry, Physical
Mariia V. Ivonina, Yuuichi Orimoto, Yuriko Aoki
Summary: This study combines quantum chemistry and machine learning to study the first hyperpolarizability (beta) in [2.2]paracyclophane-containing push-pull compounds. By establishing a neural network model and using a genetic algorithm to select relevant molecular descriptors, accurate predictions of beta values for long molecules were achieved. The research reveals that the alternating donor/acceptor pattern in the studied systems results in unequal beta responses.
JOURNAL OF CHEMICAL PHYSICS
(2021)
Article
Chemistry, Inorganic & Nuclear
Junki Ochi, Kazuo Tanaka, Yoshiki Chujo
Summary: This study demonstrates that emission annihilation can occur through bond elongation in certain aryl-substituted o-carboranes, independent of rotation. Introducing bulky substituents can suppress bond elongation and achieve emission color tuning. It is the first example to prove that excitation decay can proceed solely through bond elongation without electronic perturbation caused by rotation.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Qi Li, Yitao Wu, Jiajun Cao, Yang Liu, Zeju Wang, Huangtianzhi Zhu, Haoke Zhang, Feihe Huang
Summary: The fabrication of single-molecule white-light emission materials through-space charge transfer (TSCT) is a highly studied topic, but preparing ideal materials is still a challenge. This study reports a bifunctional pillar[5]arene with aggregation-induced emission (AIE) property, which achieves intramolecular TSCT emission through its twisted conformation and non-conjugated structure, and triggers emission through the AIE feature and responsiveness to viscosity and polar guests.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Nanoscience & Nanotechnology
Weijie Li, Xin Lu, Jiatian Wu, Ajit Srivastava
Summary: Research has shown that many-body interactions among interlayer excitons in a WSe2/MoSe2 heterobilayer can induce a valley Zeeman splitting that is comparable in strength to a magnetic field of approximately 6 T, and the g-factor of the valley Zeeman splitting can be tuned by incident power, providing an effective way to control the valley pseudospin.
NATURE NANOTECHNOLOGY
(2021)
Article
Nanoscience & Nanotechnology
Yongjun Song, Mingxing Tian, Renyou Yu, Lei He
Summary: In this study, a fixing acceptor design was used to develop a series of efficient TSCT TADF emitters, exhibiting excellent performance in doped films. The research confirmed the significance of cofacial conformation and TSCT in these emitters.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Polymer Science
Chin-Yang Yu, Shih-Hao Wen, Sheng-Hao Yu, Chao-Chi Wang
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
(2018)
Article
Chemistry, Multidisciplinary
Suyong Shin, Ming-Long Gu, Chin-Yang Yu, Jongseol Jeon, Eunji Lee, Tae-Lim Choi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Polymer Science
Chin-Yang Yu, Alis Shano Godana
EUROPEAN POLYMER JOURNAL
(2018)
Article
Polymer Science
Chin-Yang Yu, Chia-Chieh Hsu
Article
Chemistry, Multidisciplinary
Chin-Yang Yu, Chia-Chieh Hsu, Hsi-Chen Weng
Article
Chemistry, Multidisciplinary
Chin-Yang Yu, Yu-Chun Lai
Article
Polymer Science
Chin-Yang Yu, Yu-Chun Lai
MACROMOLECULAR CHEMISTRY AND PHYSICS
(2018)
Article
Polymer Science
Yu-Wei Tu, Chao-Chi Wang, Alis Shano Godana, Chin-Yang Yu
EUROPEAN POLYMER JOURNAL
(2019)
Article
Polymer Science
Chao-Chi Wang, Chin-Yang Yu
Article
Polymer Science
Alis Shano Godana, Chin-Yang Yu
Article
Polymer Science
Ching-Ju Liu, Chao-Chi Wang, Dong-Lin Kuo, Chin-Yang Yu
Article
Chemistry, Multidisciplinary
Tsegaye Belege Atisme, Chin-Yang Yu, Eric Nestor Tseng, Yi-Che Chen, Pei-Kai Hsu, Shih-Yun Chen
Article
Polymer Science
Hsien-Tang Chiu, Chin-Yang Yu, Chang-Min Huang, Bang-Shuan Lin
JOURNAL OF APPLIED POLYMER SCIENCE
(2020)
Article
Polymer Science
Chia-Jung Lin, Yi-Hao Lin, Tai-Chin Chiang, Chin-Yang Yu
Summary: Well-defined norbornene-based homopolymers and block copolymers with low polydispersity index and close to theoretical molecular weight were synthesized using the third-generation Grubbs' initiator. These polymers exhibit aggregation-induced emission characteristics and high emission in solid and aggregate states. They show strong sensing ability for aniline in the aggregated state with a detection limit of 5 x 10-6 M.
Article
Polymer Science
Van Hoang-Khang Phan, Yi-Hsin Tai, Tai-Chin Chiang, Chin-Yang Yu
Summary: This article focuses on the synthesis and properties of random copolymers poly(l-lactide-r-glycolide) and block copolymers poly(l-lactide-b-glycolide). The results show that block copolymers have better thermal stability and crystallinity compared to random copolymers, and also exhibit higher hydrophilicity.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)