Article
Biochemistry & Molecular Biology
Shuping Wu, Kanghui Li, Weijian Shi, Jiawei Cai
Summary: A novel nanofibrous membrane was prepared to remove heavy metal ions and organic pollutants from water. The membrane exhibited excellent adsorption and retention performance for target ions and dyes.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Chemistry, Applied
Yuhui Cui, Guozhen Li, Hanzhu Wu, Siyu Pang, Yan Zhuang, Zhihao Si, Xinmiao Zhang, Peiyong Qin
Summary: By optimizing the concentration of acetone additive, coagulation bath composition and evaporation time, the gas separation performance and application value of the Kapton membrane can be enhanced.
REACTIVE & FUNCTIONAL POLYMERS
(2023)
Article
Materials Science, Characterization & Testing
Yuanfei Ge, Xiangsong Chen, Xiangqin Wang, Lixia Yuan, Jinyong Wu, Jianming Yao
Summary: The CS-NeuAC hydrogel prepared from chitosan and N-acetylneuraminic acid exhibited favorable swelling behavior, mechanical properties, and antibacterial activity.
Article
Chemistry, Physical
Xiaohui He, Jianhua Zou, Yufei Wen, Bin Wu, Xiujing Zang, Jiahao Deng, Zengwei Qin, Guoxiao Yang, Jiang Xu, Defu Chen
Summary: A new anion exchange membrane material with high conductivity and stability was obtained through controllable addition copolymerization using a specific catalyst system.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Biochemistry & Molecular Biology
Yunwu Yu, Chunyang Xie, Yan Wu, Peng Liu, Ye Wan, Xiaowei Sun, Lihua Wang, Yinan Zhang
Summary: A novel composite membrane was developed by casting chitosan and polyvinyl alcohol on a glass fiber microporous membrane. The addition of chitosan improved the CO2 permeance and selectivity due to the favorable CO2 affinity of the polymer coating. Chemical structure analysis showed no change after heat treatment, while SEM images revealed a dense surface of the composite membranes. The CO2 permeance and selectivity were further enhanced after wetting and heat treatment.
Article
Biotechnology & Applied Microbiology
Truc-Mai T. Nguyen, Jein-Wen Chen, Minh-Thuan Pham, Ha Manh Bui, Chien-Chieh Hu, Sheng-Jie You, Ya-Fen Wang
Summary: Inspired by the adhesive ability of marine mussels, researchers have investigated the H2 separation performance of ZIF-8 membranes synthesized on polydopamine-functionalized stainless-steel-nets. The membrane achieves high separation efficiency and permeability due to the promotion of nucleation and continuous development of the ZIF-8 layer by the polydopamine layer. Additionally, the study explores the influence of ZIF-8 solution concentration and compares self-synthesized ZIF-8 particles with commercial ones.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Article
Engineering, Environmental
Huihui Deng, Jing Huang, Cunqi Qin, Tianhui Xu, Huagang Ni, Peng Ye
Summary: Graphene-based membranes, especially the composite membrane of hydroxylated graphene (GOH) and graphene oxide (GO), exhibit high water permeability and effective molecule retention, making them suitable for separation applications.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Polymer Science
Byeong Ju Park, Na Un Kim, Chang Soo Lee, Jong Hak Kim
Summary: Alcohol-soluble comb copolymers were synthesized from rubbery POEM and glassy PAcAm, showing high CO2 permeability and CO2/N2 selectivity in a mechanically strong free-standing membrane. The enhanced performance was attributed to an effective CO2-philic pathway for the ethylene oxide group in POEM and prevention of N2 permeability by PAcAm chains.
Review
Chemistry, Multidisciplinary
Xiaojun Sun, Mengting Di, Jie Liu, Li Gao, Xiaoming Yan, Gaohong He
Summary: This review article introduces covalent organic frameworks (COFs), which are porous crystalline polymeric materials formed by the covalent bonding of organic units. The diverse library of organic units gives COFs species diversity, easily tuned pore channels, and pore sizes. The periodic arrangement of organic units in COFs provides regular and highly connected pore channels, leading to the rapid development of COFs in membrane separations. The preparation strategies of continuous COF membranes are highlighted, and the applications in separation fields are discussed.
Review
Chemistry, Multidisciplinary
Zhe Yuan, Guangwei He, Sylvia Xin Li, Rahul Prasanna Misra, Michael S. Strano, Daniel Blankschtein
Summary: This article discusses recent modeling and experimental advances in nanoporous atomically thin membranes for gas separations. It highlights the advantages and challenges involved, as well as proposes future directions for development.
ADVANCED MATERIALS
(2022)
Article
Engineering, Chemical
Jen-Yu Lee, Jin-Yun Zhan, Micah Belle Marie Yap Ang, Shih-Chieh Yeh, Hui-An Tsai, Ru-Jong Jeng
Summary: In this study, spirobisindane-functionalized graphene oxide (SFGO)/polyimide (Matrimid 5218) solutions were used to create nanocomposite membranes for alcohol dehydration. The membranes showed improved performance with the addition of spirobisindane structure, and different levels of dehydration were achieved depending on the alcohol feed solutions used. The modified membranes exhibited stability under various operating conditions, indicating potential for long-term use.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Mengyang Lu, Hanmin Zhang
Summary: In this study, an integrated and self-standing membrane of nano-ZnCeOx combined with porous graphitic carbon nitride (ZnCe@PCNM) was successfully fabricated. The membrane showed excellent photocatalytic and membrane separation performances, with good self-cleaning ability and high separation efficiency. It has great potential for practical applications.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Environmental Sciences
Zarrar Salahuddin, Sarah Farrukh, Rahim Jan, Atif Ayub, Arshad Hussain, Maxime Pontie, Anas Ahmed, Muhammad Mubashir
Summary: This study successfully modifies cellulose acetate membranes by incorporating high aspect ratio h-BN nanosheets, leading to a reduction in CO2 gas permeability. The dimensional analysis, functional group analysis, and crystalline phase analysis of nanocomposites were conducted using SEM, FT-IR spectroscopy, and XRD, respectively. Tensile testing and tribological property analysis showed that the nanocomposite samples exhibited higher mechanical strength and adhesion compared to pristine samples.
Article
Thermodynamics
Hongming Fu, Yubin Shen, Zhaohao Li, Heng Zhang, Haiping Chen, Dan Gao
Summary: This study investigates the hydrophobic modification of Al2O3 ceramic membranes for CO2 capture. The modified membranes exhibit improved carbon capture performance, with increased mass transfer coefficient and capture efficiency. Furthermore, the superhydrophobic membranes show excellent corrosion resistance.
Article
Engineering, Chemical
Lei Wang, Lei Wang, Lingping Li
Summary: The PVC-LMZO membrane has high selectivity and cycling performance, making it suitable for extracting lithium from salt lake brine.
Review
Materials Science, Multidisciplinary
Diksha Yadav, Swapnali Hazarika, Pravin G. Ingole
Summary: This review article provides an overview of the current advances of NF membranes in plant extracts, food, and dairy industries, highlighting the importance of finding solutions for fouling issues and discussing future prospects.
EMERGENT MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Moucham Borpatra Gohain, Sachin Karki, Diksha Yadav, Archana Yadav, Neha R. Thakare, Swapnali Hazarika, Hyung Keun Lee, Pravin G. Ingole
Summary: Polymer-based thin film nanocomposite (TFN) membrane technologies are of great interest in improving separation properties. Functional nanomaterials incorporated in TFN membranes enhance permeance and selectivity. This study successfully developed TFN membranes for separating low concentration solutions and achieved outstanding separation values.
Article
Engineering, Environmental
Sachin Karki, Pravin G. Ingole
Summary: The vapor phase interfacial polymerization method was used to develop thin-film nanocomposite and thin-film composite membranes. TiO2 nanoparticles were incorporated to tackle heavy metal pollution, and functionalized TiO2 nanoparticles were used to enhance interaction with the matrix phase. The TFN membranes showed high rejection rates for different ions and improved antifouling properties.
CHEMICAL ENGINEERING JOURNAL
(2022)
Correction
Ecology
Kripal Singh, Chaeho Byun, Faizal Bux
ECOLOGICAL ENGINEERING
(2022)
Article
Environmental Sciences
Shalini Dhyani, Harini Santhanam, Rajarshi Dasgupta, Dhanya Bhaskar, Indu K. Murthy, Kripal Singh
Summary: Land degradation caused by large-scale coal mining is a major ecological issue in India, leading to biodiversity loss and extreme weather events. India has made bold pledges to address climate change and commit to net-zero emissions by 2070. The government is increasing support for mine closure and land restoration, and international and private finances can help achieve the goals. Embedding diverse knowledge systems and using systems thinking approach are important for achieving climate and land degradation neutrality targets.
LAND DEGRADATION & DEVELOPMENT
(2023)
Article
Green & Sustainable Science & Technology
Sunidhi Singh, Shalini Dhyani, Ramesh Janipella, Soumya Chakraborty, Paras Ranjan Pujari, V. M. Shinde, Kripal Singh
Summary: Land degradation due to mining is a significant concern, impacting biodiversity and ecosystem services. This study conducted biomonitoring of metals in a mine void and found high concentrations of metals, such as iron, in both soil and plants. The research highlights the importance of corporate commitment to regular biomonitoring and land restoration for degraded mining areas.
Article
Engineering, Chemical
Sachin Karki, Moucham Borpatra Gohain, Diksha Yadav, Neha R. Thakare, Radheshyam R. Pawar, Swapnali Hazarika, Pravin G. Ingole
Summary: Novel TFN membranes were developed by incorporating amine-rich synthetic talc (NHST) nanosheets within diethylenetriamine (DETA) and trimesoyl chloride (TMC) monomers over a polydopamine (PDA) coating layer. The in-situ synthesized NHST nanosheet phases were confirmed by various characterization techniques, and the results showed improved permeability and rejection with a small amount of NHST doping in the TFN layer.
Article
Polymer Science
Pravin G. G. Ingole
Summary: Polyamide-based thin film nanocomposite (TFN) membranes were prepared by incorporating nanoparticles in an aqueous phase and an organic phase by interfacial polymerization (IP) method. APTMSH was added in the aqueous phase to enhance the TFN layer interfacial compatibility. The TFN membranes showed improved gas permeance and selectivity for binary mixture gas separation.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Ashmita Mukherjee, Sreyasi Pal, Shivangi Parhi, Sachin Karki, Pravin G. Ingole, Paulomi Ghosh
Summary: In recent years, there has been a global focus on the extraction of bioresources from biowaste using green chemistry for the production of materials, driven by the increasing awareness of sustainability. This study introduces a benign process using an ionic liquid to simultaneously extract keratin and melanin from human hair. The extracted keratin demonstrates hemocompatibility, making it suitable for blood-contacting biomaterials, while the extracted melanin retains its morphology and shows free-radical scavenging activity. The reusable ionic liquid used in the extraction process can potentially be applied in bioelectronics.
Review
Multidisciplinary Sciences
Jonathan Morizet-Davis, Nirvana A. Marting Vidaurre, Evelyn Reinmuth, Esmaeil Rezaei-Chiyaneh, Valentin Schlecht, Susanne Schmidt, Kripal Singh, Ricardo Vargas-Carpintero, Moritz Wagner, Moritz von Cossel
Summary: This paper reviews and evaluates the main ecosystem services at the farm level, including provisioning, regulating, habitat, and cultural services. It also discusses the trade-offs and evaluation of these services, and proposes a stakeholder approach framework for farm-level ecosystem services.
Article
Agricultural Engineering
Kripal Singh, Ram Swaroop Meena, Sandeep Kumar, Shalini Dhyani, Seema Sheoran, Har Mohan Singh, Vinayak V. Pathak, Zaira Khalid, Anita Singh, Kapil Chopra, Somvir Bajar, Faiz Ahmad Ansari, Sanjay Kumar Gupta, Sunita Varjani, Richa Kothari, Vineet Veer Tyagi, Bhaskar Singh, Chaeho Byun
Summary: This article reviews the development of renewable energies in India after the Paris Climate Agreement, specifically focusing on solar energy's massive success and limited investment in other renewable sectors. It highlights India's ambitious plans to phase down coal use and become a carbon-neutral economy, as well as the highly ambitious commitments made at COP26.
BIOMASS & BIOENERGY
(2023)
Article
Engineering, Environmental
Diksha Yadav, Sachin Karki, Moucham Borpatra Gohain, Pravin G. Ingole
Summary: In this study, vapor-phase interfacial polymerization (VP-IP) method was used to fabricate thin-film composite (TFC) and thin-film nanocomposite (TFN) nanofiltration (NF) membranes for the removal of micropollutants DIC and TRI. The TFN membranes showed excellent removal efficiency and antifouling properties, indicating their potential for removing emerging micropollutants from water.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Neha R. Thakare, Pravin G. Ingole, Swapnali Hazarika
Summary: In this study, copper and silver nanoparticles were synthesized using Polygonum microcephalum. This is the first report on the synthesis of silver nanoparticles and copper oxide nanoparticles from Polygonum microcephalum. The synthesized silver nanoparticles showed toxicity against certain bacteria, while the copper oxide nanoparticles were not effective due to their larger size.
Article
Engineering, Environmental
Bhavesh Borban, Moucham Borpatra Gohain, Diksha Yadav, Sachin Karki, Pravin G. Ingole
Summary: Electrospun nanofiber membranes, with their unique properties such as high surface area-to-volume ratio, tunable pore size, and exceptional mechanical strength, have diverse applications in fields including wastewater treatment, food packaging, healthcare, and catalytic processes, effectively addressing complex challenges.
JOURNAL OF HAZARDOUS MATERIALS ADVANCES
(2023)
Article
Green & Sustainable Science & Technology
Kripal Singh, Faiz Ahmad Ansari, Kapilkumar Nivrutti Ingle, Sanjay Kumar Gupta, Jitendra Ahirwal, Shalini Dhyani, Shraddha Singh, P. C. Abhilash, Ismael Rawat, Chaeho Byun, Faizal Bux
Summary: Microalgae have significant potential in applications such as wastewater treatment, agricultural productivity, and biomass production, contributing to global sustainability and socio-economic development.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)