Article
Chemistry, Physical
Simao P. Cardoso, Tiago L. Faria, Eduarda Pereira, Ines Portugal, Claudia B. Lopes, Carlos M. Silva
Summary: The study demonstrated that Na-ETS-4 is highly selective for Hg2+ and can exchange over 90% of mercury in the fluid phase. The system with Hg2+/Na+/ETS-4 required more time to reach equilibrium in the presence of Na+ compared to TPA(+). The modeling based on mass action law and Maxwell-Stefan formalism successfully described the kinetic curves of mercury removal.
Article
Chemistry, Multidisciplinary
Tinsley Elizabeth Benhaddouch, Shekhar Bhansali, Dongmei Dong
Summary: This study investigates the impact of electrolyte on the performance of electrochromic devices by comparing aqueous and non-aqueous electrolytes. The results show that although the aqueous electrolyte has a smaller redox potential window, it exhibits a higher current density compared to the non-aqueous electrolyte. Furthermore, the chemical nature of the electrolyte significantly affects the electrochemical kinetics at the electrolyte/electrode interface.
Article
Materials Science, Ceramics
Yuma Sasamura, Takashi Kojima, Naofumi Uekawa
Summary: In this study, a stable sol of alpha-Ni(OH)2 nanoparticles was successfully prepared by adding sorbitol. The resulting sol can be used to prepare thin films with reversible electrochromic characteristics.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Environmental Sciences
Jingmin Yan, Zhengchen Li, Xiang Liu, Peng Qian, Xikai Liu, Shufeng Ye
Summary: In this study, CoAl-layered double hydroxide (CoAl-LDH) was synthesized and used as an adsorbent for removing thiocyanate (SCN-) from water. The CoAl-LDH showed high removal efficiencies for SCN- under a wide range of pH and ambient temperature conditions. The adsorption mechanism of SCN- by CoAl-LDH involved interlayer ion exchange, electrostatic interactions, and surface ligand exchange. The CoAl-LDH could be regenerated and reused up to four cycles, showing great potential for SCN- removal from aqueous solution.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Engineering, Chemical
Asiyeh Kheradmand, Mehrdad Negarestani, Sima Kazemi, Hadi Shayesteh, Shahrzad Javanshir, Hossein Ghiasinejad, Edris Jamshidi
Summary: In this study, a magnetic core-shell rhamnolipid (MCSR) intercalated cobalt/aluminum layered double hydroxide (LDH) was used for water remediation and rifampin (RIF) removal. The biosurfactants, including rhamnolipid (RL), demonstrated low toxicity and environmental compatibility, and promoted the removal efficiency of the adsorbent. The adsorption process was optimized by considering factors such as pH, initial RIF concentration, contact time, and adsorbent dosage. The RIF removal efficiency was found to be 96%, with a maximum adsorption capacity of 221.30 mg/g. The magnetic property of MCSR-LDH allowed for easy recovery and regeneration of the adsorbent.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Green & Sustainable Science & Technology
Lei Wang, Mohammad Torkamanzadeh, Ahmad Majed, Yuan Zhang, Qingsong Wang, Ben Breitung, Guang Feng, Michael Naguib, Volker Presser
Summary: Electrochemical ion separation is a promising technology for recovering valuable ionic species from water. This study investigates the selective behavior of Ti3C2Tz MXene towards alkali and alkaline earth cations. The results show that Ti3C2Tz exhibits a time-dependent selectivity feature, preferring K+ in the early stage and ultimately preferring Ca2+ and Mg2+.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Review
Engineering, Environmental
Lukasz Stala, Justyna Ulatowska, Izabela Polowczyk
Summary: Pollution by heavy metal ions in aqueous systems has gradually gained researchers' attention. Technologies such as chemical precipitation, adsorption, membrane filtration, and ion exchange have been developed for ion removal, with a focus on materials like polyampholytes. Recent publications show promising properties of experimental polyampholytes in toxic metal ion removal, encouraging further research in this area.
Article
Environmental Sciences
S. P. Keerthana, R. Yuvakkumar, P. Senthil Kumar, G. Ravi, Dhayalan Velauthapillai
Summary: In this study, the performance of pure copper hydroxide and copper hydroxide prepared with different proportions of sodium dodecyl sulphate (SDS) was investigated, with the 2% SDS-assisted sample showing superior photocatalytic activity. Formation of nanoclusters and nanosheets was confirmed through SEM analysis.
ENVIRONMENTAL RESEARCH
(2021)
Article
Metallurgy & Metallurgical Engineering
Fatemeh Sadat Hoseinian, Bahram Rezai, Mehdi Safari, David Deglon, Elaheh Kowsari
Summary: This study investigated the optimal conditions for the combined separation of nickel and zinc ions using Trien and SDS, showing that nickel ion removal is higher than zinc ions, which is opposite to the order of increasing crystal ionic radius.
Article
Chemistry, Medicinal
Fumihiko Ogata, Yugo Uematsu, Yuhei Kobayashi, Yuuka Izutani, Chalermpong Saenjum, Megumu Toda, Masashi Otani, Takehiro Nakamura, Naohito Kawasaki
Summary: In this study, complex nickel-aluminum hydroxides were prepared at different molar ratios, with NA41 showing the highest adsorption capability on As(III). The equilibrium adsorption of As(III) using NA41 was achieved within 24h, following a pseudo-second-order model, and the adsorption isotherms were well described by both the Langmuir and Freundlich equations. The optimal pH condition for removal of As(III) using NA41 was found to be approximately 6-8.
CHEMICAL & PHARMACEUTICAL BULLETIN
(2021)
Article
Nuclear Science & Technology
Chun Ping Huang, Hsin Yu Chen, Wei Hsiang Lin
Summary: Two methods, fluidization with a column and immersion into a solution, were investigated for the separation of anion and cation exchange resins. These methods demonstrated effective separation, reducing the costs of radioactive waste disposal.
PROGRESS IN NUCLEAR ENERGY
(2022)
Article
Chemistry, Applied
Yuan Chen, Xiaoguo Ma, Junbiao Peng
Summary: The nano-sized magnetic ion-imprinted polymers (MIIPs) synthesized using chitosan showed high sorption selectivity for Ni(II) and could efficiently recover the adsorbed ions. The sorption process was quick, endothermic, and could be described by Langmuir isotherm model and pseudo-second-order kinetic model. MIIPs proved to be a suitable adsorbent for selective removal and recovery of low-concentration Ni(II) ions from wastewaters.
CARBOHYDRATE POLYMERS
(2021)
Article
Engineering, Environmental
Weifeng Liu, Zhuolin An, Lei Qin, Meiling Wang, Xuguang Liu, Yongzhen Yang
Summary: The study proposed an efficient electrochemically assisted imprinting and elution strategy, successfully synthesizing a novel ion imprinted film (Cu2+-IIF) with over 90% removal efficiency for Cu2+ at 5 ppm concentration. Cu2+-IIF exhibited a high adsorption capacity of 7.57 mg g(-1) and showed good selectivity towards Cu2+.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Ceramics
Farida khan, A. Naeem, Israf Ud Din, T. Saeed, Mshari A. Alotaibi, Abdulrahman I. Alharthi, Asad Habib, Tabassum Malik
Summary: In this study, hexagonal boron nitride (h-BN) was synthesized and used as an efficient sorbent for the uptake of Cd2+ ions. The kinetics and sorption studies showed that the process of Cd2+ sorption remained endothermic, and the Ho's model was found to best interpret the adsorption kinetic data. The physicochemical properties of h-BN were characterized before and after adsorption, showing its effectiveness as an adsorbent for Cd2+ ions in aqueous media.
CERAMICS INTERNATIONAL
(2021)
Article
Environmental Sciences
Detian Li, Hongbiao Cui, Yueqin Cheng, Lihong Xue, Bingyu Wang, Huayong He, Yun Hua, Qingnan Chu, Yanfang Feng, Linzhang Yang
Summary: Chemical aging of hydrochar can effectively enhance its adsorption capacity by increasing the specific surface area and oxygen-containing functional groups to combine with Cd2+, while removing Cd2+ from water through ion exchange.
ENVIRONMENTAL POLLUTION
(2021)
Article
Chemistry, Multidisciplinary
Weidong Wen, Ping Yan, Wanping Sun, Yitong Zhou, Xin-Yao Yu
Summary: The metastable phase Cu synthesized through O-2/Ar plasma oxidation and subsequent electro-reduction exhibits superior performance in electrocatalytic nitrate reduction reaction, with high selectivity and efficiency.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Guanru Chang, Yitong Zhou, Jianghao Wang, Hui Zhang, Ping Yan, Hao Bin Wu, Xin-Yao Yu
Summary: This study reports a facile one-pot synthesis of RuO2-incorporated NiFe-metal organic framework (RuO2/NiFe-MOF) with a unique nanobrick-nanosheet heterostructure as a precatalyst. The as-reconstructed RuO2/NiFeOOH exhibits outstanding alkaline OER activity and stability due to the synergistic interaction between RuO2 and NiFeOOH.
Article
Chemistry, Multidisciplinary
Ping Yan, Tao Yang, Minxi Lin, Yanan Guo, Zipeng Qi, Qiquan Luo, Xin-Yao Yu
Summary: A novel beta-Ni(OH)2/Ni-Ru SAs heterostructured nanosheet array is developed through plasma activation and Ru single atoms doping, which greatly enhances the HER activity of Ni(OH)2. The heterostructure exhibits low overpotential and small Tafel slope in alkaline solution, and also demonstrates excellent HER performance in alkaline seawater and neutral solutions. The plasma activation and Ru SAs doping play important roles in enhancing water adsorption and accelerating the kinetics of water dissociation.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ranran Tang, Yu Yang, Yitong Zhou, Xin-Yao Yu
Summary: A rational and versatile design strategy is proposed to boost the pH-universal HER activity of Ru clusters by exploring supports with both high work function and facilitated water dissociation ability. Heterostructured Mo2C nanoparticles-Ru clusters anchored carbon spheres (Mo2C-Ru/C) are designed and prepared guided by theoretical calculations. Mo2C-Ru/C exhibits low overpotential and small Tafel slope in alkaline solution, as well as excellent activity in alkaline seawater, acidic, and neutral solutions. Mo2C-Ru/C also shows high discharge power density and excellent stability for simultaneous generation of electricity and hydrogen (H-2) in an alkaline-acid Zn-H2O battery.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Physics, Applied
Yanqiu Yang, Zhengzhao Wang, Ping Yan, Xin-Yao Yu
Summary: Layered double hydroxides (LDHs) have large specific surface areas and rich metal redox sites, making them potentially suitable oxygen evolution reaction catalysts. However, they often exhibit poor hydrogen evolution reaction (HER) activity due to limited conductivity and active sites. In this study, a plasma engraving strategy was developed to enhance the HER activity of NiFe LDH. The plasma engraving process improved the conductivity and active sites by reducing Ni2+ to Ni nanoparticles, generating more oxygen vacancies, and exfoliating nanosheets into thinner ones. The plasma-engraved NiFe LDH (PEH) showed enhanced HER activity with low overpotential and small Tafel slope, outperforming regular NiFe LDH. Furthermore, PEH also displayed excellent HER activity in alkaline real seawater and overall water splitting.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Physical
Yonghui Guan, Lin Dong, Luchun Qiu, Ping Yan, Xin-Yao Yu
Summary: The hydrogen evolution reaction (HER) has so far been studied mainly in strong acidic/alkaline electrolytes. However, conducting the HER in extreme conditions has proven to have several drawbacks such as electrolyzer corrosion, water pollution, and the use of expensive membranes. Conducting the HER in neutral media is a desirable solution to these issues but faces the challenge of slow kinetics. In this study, a plasma-assisted approach is used to synthesize an efficient electrocatalyst with multiple active components for neutral HER.
Article
Chemistry, Physical
Wenxuan Hou, Kang Peng, Shikuo Li, Fangzhi Huang, Baojun Wang, Xinyao Yu, Hengxiu Yang, Hui Zhang
Summary: To achieve exceptional electromagnetic wave absorption properties, it is crucial to design the microstructure and modify the components of composites. Metal-organic frameworks (MOFs), with their unique metal-organic crystalline coordination, tunable morphology, high surface area, and well-defined pores, have been recognized as promising precursors for electromagnetic wave absorption materials. However, the inadequate contact abilities between adjacent MOFs nanoparticles result in poor electromagnetic wave dissipation capacity at low filler loading, posing a significant challenge in breaking the size effect of nanoparticles.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Correction
Chemistry, Multidisciplinary
Jingyi Shi, Niannian Wang, Wenhao Du, Yi Feng, Xin-Yao Yu
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Qi Qi, Duo Shao, Yitong Zhou, Qi Wang, Xin-Yao Yu
Summary: By using a N2/H2 plasma activation strategy, multiple HER active species (Ni, Ni3N, and MoNi4) are implanted in molybdenum-based polyoxometalate (POM)-encapsulated Ni MOF nanosheet arrays, resulting in enhanced conductivity and increased active sites. The plasma-activated Ni MOF/POM exhibits splendid HER activity and long-term stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Jingyi Shi, Niannian Wang, Wenhao Du, Yi Feng, Xin-Yao Yu
Summary: The exploration of high-performance trifunctional electrocatalysts for ORR, OER, and HER is crucial for sustainable energy technologies. In this study, porous RuO2-Co3O4/C (RuCoO/C) nanocubes were synthesized using a facile template-engaged approach as advanced trifunctional electrocatalysts. The RuCoO/C nanocubes exhibited high performance in ORR, OER, and HER, as well as excellent stability. When applied in ZABs and water electrolysis, the RuCoO/C nanocubes demonstrated high efficiency and splendid stability.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Yanrui Xu, Wangjian Liu, Zihang Xu, Yitong Zhou, Xin-Yao Yu
Summary: We report an effective catalyst composed of in situ reconstructed AgZn3 nanoparticles and Zn nanoplates for syngas synthesis, showing tunable H2/CO ratios and high Faraday efficiency. Experimental and theoretical results suggest that the Zn site in AgZn3 nanoparticles and the hollow site between Ag and Zn in AgZn3 are the active sites for CO and H2 generation, respectively. This work has important implications for designing dual site catalysts for CO2 electroreduction to tunable syngas.
CHEMICAL COMMUNICATIONS
(2023)
Correction
Chemistry, Physical
Duo Shao, Qi Wang, Xianzhi Yao, Yitong Zhou, Xin-Yao Yu
Summary: This paper discusses the phase-engineering correction for efficient hydrogen evolution and hydrazine-assisted water splitting in seawater using nickel hydroxide in the Ni/Ni(OH)2 interface.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Chemistry, Physical
Guanru Chang, Hui Zhang, Xin-Yao Yu
Summary: Two-dimensional metal-organic frameworks (MOFs) and their derivatives have been extensively studied as (pre)electrocatalysts for oxygen evolution reaction (OER). These materials exhibit excellent OER performance and have potential applications in energy conversion and storage technologies.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Duo Shao, Qi Wang, Xianzhi Yao, Yitong Zhou, Xin-Yao Yu
Summary: The alkaline hydrogen evolution reaction (HER) activity of layered metal hydroxides is optimized by phase engineering and loading Ni nanoparticles, particularly beta-Ni(OH)(2), to improve the electrical conductivity and Volmer step. The constructed heterostructured Ni/beta-Ni(OH)(2) nanosheet arrays (NSAs) exhibit enhanced HER activity and hydrazine oxidation reaction activity compared to Ni/alpha-Ni(OH)(2) NSAs. In hydrazine-assisted water splitting, Ni/beta-Ni(OH)(2) NSAs require a small voltage to achieve high current densities.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Luchun Qiu, Qi Wang, Ping Yan, Xin-Yao Yu
Summary: In this work, a chemical-physical synergistic etching strategy is developed to enable the deep reconstruction of NiFe PBA nanocubes, thus promoting the OER activity. The NiOOH/FeOOH nanoboxes obtained after etching exhibit a low overpotential and excellent peak power density and cycling stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)