期刊
NEW JOURNAL OF CHEMISTRY
卷 33, 期 2, 页码 246-253出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b819604d
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资金
- Institut Universitaire de France (IUF)
- Agence Nationale de la Recherche (ANR) [ANR-06-NANO-026-02]
- Universite Bordeaux 1
- Centre National de la Recherche Scientifique (CNRS)
Styrenic dendrons functionalized with ferrocenyl and chloromethylsilyl termini were synthesized and polymerized by the AIBN-initiated radical polymerization procedure yielding a ferrocenyl dendronized polymer and a chloromethylsilyl dendronized polymer, respectively. The latter polymer was functionalized with ferrocenyl groups using click'' chemistry. The ferrocenyl dendronized polymers are soluble in common organic solvents such as tetrahydrofuran, dichloromethane, and chloroform. They show a reversible ferrocenyl wave in cyclic voltammetry (CV) and form derivatized Pt electrodes. Their sizes and shapes were examined by size exclusion chromatography (SEC), atomic force microscopy (AFM), dynamic light scattering (DLS) and DOSY H-1 NMR spectroscopy.
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