期刊
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷 136, 期 -, 页码 1718-1727出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2014.10.073
关键词
Mercaptoacetohydrazide; Complexes; Spectra; Thermal analysis; Cytotoxic and antioxidant activity; Solution chemistry
类别
Complexes of VO2+, Cr3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+ and Hg2+ ions with N-(2,4-dinitrophenyl)-2-mercaptoacetohydrazide (H2L) have been prepared and characterized on the basis of elemental analysis, molar conductance, thermal (TGA, DTGA), spectral (IR, NMR, UV-Visible, MS) and magnetic measurements. The IR spectra show that H2L behaves in a mononegative and/or binegative bidentate manner. The sulfate bridged the two complex molecules in [Cu(HL)(H2O)(2)(1/2SO(4))]center dot 3H(2)O. The acetate functions as a monodentate in [Ni(HL)(OAc)(H2O)(3)] and [Cr(HL)(OAc)(2)(H2O)(EtOH)]. Different stereochemistries are proposed: octahedral for Cr(III), Ni(II), Hg(II) and [Cu(HL)(H2O)(2)(SO4)(0.5)]center dot 3H(2)O, square-based pyramid for [VO(HL)(2)]-EtOH, square-planar for [Co(L)(EtOH)(H2O)]center dot H2O, [Cu(L)(H2O)(2)] and tetrahedral for [Zn(L)(EtOH)(H2O)], [Cd(L)(EtOH)(H2O)] and [Cu-2(HL)(H2O)(6)]Cl-3 center dot H2O according to the data of electronic spectra and magnetic measurements. The TGA data support the formula and indicate the outer and inner solvents as well as the final residue. The thermodynamic parameters are calculated using the Coats-Redfern and Horowitz-Metzger methods. H2L and [Zn(L)(EtOH)(H2O)] showed the highest cytotoxic activity while H2L has a higher antioxidant activity than ascorbic acid. The ionization constant of the ligand and the stability constant of the Cu(II) H2L in absence and presence of hexamine buffer were calculated. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据