4.7 Article

Unraveling the high performance of tri-iodide perovskite absorber based photovoltaics with a non-polar solvent washing treatment

期刊

SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 141, 期 -, 页码 309-314

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.solmat.2015.06.002

关键词

2D XRD; Tr-iodide perovskite film; Photovoltaics

资金

  1. National Science Council [NSC 101-2731-M-008-002-MY3]

向作者/读者索取更多资源

A comprehensive study was carried out to understand the formation of a crystalline tri-iodide perovskite absorber (TPA) on top of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). Scanning electron microscopy, two-dimensional X-ray diffraction and nanosecond time-resolved photoluminescence were used to explore the correlation between the surface morphology and the exciton lifetime in TPA fabricated with and without the in-situ toluene washing treatment. The toluene washing treatment decreases the crystallinity (exciton lifetime) of TPA and improves the TPA coverage on the non-crystalline PEDOT:PSS surface. The high average power conversion efficiency (PCE) of 10.61% achieved can be explained as due to the efficient exciton dissociation at the interface between the TPA and the PEDOT:PSS. The experimental results show that the PCE can be further improved when the crystallinity of TPA and the TPA coverage on PEDOT:PSS are simultaneously optimized. (C) 2015 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Physics, Multidisciplinary

A Voyage from Plasmonic to Hybrid Waveguide Refractive Index Sensors Based on Wavelength Interrogation Technique: a Review

Rammani Adhikari, Zen Sbeah, Diksha Chauhan, Sheng Hsiung Chang, Ram Prakash Dwivedi

Summary: This study introduces the theories and principles of surface plasmon polariton generation and waveguide construction, and discusses the design structures that generate various optical resonances for sensing refractive index and temperature variation. The investigation focuses on plasmonics refractive index sensors based on Bragg grating structures and resonators, and the comparison of metal-insulator-metal-resonators architecture in terms of sensitivity and figure of merit. The study also presents hybrid plasmonic waveguides that significantly improve the figure of merit and quality factor as compared to plasmonic waveguide-based sensors, while maintaining ease of fabrication due to their CMOS compatibility.

BRAZILIAN JOURNAL OF PHYSICS (2022)

Article Engineering, Environmental

Facile synthesis of spiro-core-based hole-transporting material for high-performance and stable perovskite solar cells

Kun-Mu Lee, Seid Yimer Abate, June Hung Yang, Wei-Hao Chiu, Seoungjun Ahn, Sie-Rong Li, Kang-Ling Liau, Yu-Tai Tao, Yan-Duo Lin

Summary: Two new spirocore-based HTMs were synthesized and used in perovskite solar cells. The experiments showed that these materials exhibited excellent thermal stability, photophysical properties, electro-chemical properties, charge-transporting abilities, and film-forming properties. The fabricated solar cells showed significantly higher power conversion efficiency compared to traditional cells, and also demonstrated better long-term stability.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Nanoscience & Nanotechnology

Improving the photovoltaic performance of inverted perovskite solar cells via manipulating the molecular packing structure of PCBM

Shou-En Chiang, Pei-Chen Lin, Jia-Ren Wu, Sheng Hsiung Chang

Summary: This study investigates the impact of the molecular packing structure of solution-processed phenyl-C61-butyric acid methyl ester (PCBM) thin film on the performance of PCBM/perovskite heterojunction solar cells by manipulating the volume ratio of chlorobenzene (CB) to bromobenzene (BrB). The results show that the formation of PCBM aggregates and the contact quality at the PCBM/perovskite interface significantly affect the key parameters of the solar cells.

NANOTECHNOLOGY (2023)

Article Engineering, Environmental

Doping engineering of carrier transporting layers for ambient-air-stable lead-free rudorffite solar cells prepared by thermal-assisted doctor blade coating

Kai -Chi Hsiao, Yen-Fu Yu, Ching-Mei Ho, Meng-Huan Jao, Yu -Hsiang Chang, Shih-Hsuan Chen, Yin-Hsuan Chang, Wei-Fang Su, Kun-Mu Lee, Ming-Chung Wu

Summary: Perovskite solar cells with high efficiency are seen as a promising solution for renewable energy, but the presence of toxic lead and its stability in the environment have raised concerns. This study focuses on using a lead-free material as the active layer in perovskite solar cells and doping the carrier transporting layers to improve efficiency. The devices showed good stability and maintained their high efficiency even after prolonged exposure to ambient conditions. These findings suggest that the lead-free perovskite material has potential for large-scale production.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Nanoscience & Nanotechnology

Dislocation characterization in c-plane GaN epitaxial layers on 6 inch Si wafer with a fast second-harmonic generation intensity mapping technique

Shou-En Chiang, Wen-Hsin Chang, Yu-Ting Chen, Wen-Chung Li, Chi-Tsu Yuan, Ji-Lin Shen, Sheng Hsiung Chang

Summary: The distributions of threading dislocations (TDs) and horizontal dislocations (HDs) in c-plane GaN epitaxial layers on a 6-inch Si wafer were determined using second harmonic generation (SHG) intensity, Raman scattering stress, photoluminescence, and reflected interference pattern. Raman scattering spectra revealed that TDs caused tensile stress in the GaN epitaxial layers while HDs caused compressive stress. Additionally, SHG intensity was found to be proportional to the stress value of the GaN epitaxial layers, providing insights into its spatial distribution. Notably, the dislocation-mediated SHG intensity mapping image of the GaN epitaxial layers on the 6-inch Si wafer could be obtained within 2 hours, making it useful for optimizing high-performance GaN-based HEMTs.

NANOTECHNOLOGY (2023)

Article Engineering, Environmental

A promising non-fullerene acceptor for near-infrared organic photodetectors operating with low dark current and high response speed

Yu-Ching Huang, Zhi-Hao Huang, Tai-Yung Wang, Priyanka Chaudhary, Jen-Fu Hsu, Kun-Mu Lee

Summary: By tuning the band gaps of their active layer materials, organic photodetectors (OPDs) can display good responses in the near-infrared (NIR) region, making them useful for applications in biomedical imaging and optical communication. In this study, we used 3TT-FIC, a non-fullerene acceptor (NFA), to develop OPDs capable of operating with extremely low dark currents and high response speeds. By fine tuning the blend ratio of the donor (PM6) and acceptor (3TT-FIC), we obtained an OPD that operated at a low dark current (7.04 x 10-10 A/ cm2) at -1 V with a high value of specific detectivity (D*) (2.6 x 1013 Jones) at the wavelength of 850 nm. We also discuss the wider applicability of 3TT-FIC and its potential as an NFA in NIR OPDs.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Physical

A Review on Metamaterial Sensors Based on Active Plasmonic Materials

Zen A. Sbeah, Rammani Adhikari, Vishal Sorathiya, Diksha Chauhan, Sheng Hsiung Chang, Ram Prakash Dwivedi

Summary: Plasmonics has attracted attention for its ability to control light flow in metamaterials. The use of active plasmonic materials allows for the mass production of low-cost, high-performance nanosized optical components for imaging, sensing, and communications. By integrating non-volatile active materials with distinct qualities, dynamic plasmonic systems can be reconfigured to provide sharper optical variations and faster phase shifting. This review focuses on metamaterial plasmonic sensors that detect changes in refractive indices, and the use of active materials to enhance sensing and light absorption.

PLASMONICS (2023)

Article Engineering, Chemical

Properties of FAPbI3-Based Alloy Perovskite Thin Films and Their Application in Solar Cells

Chia-Lung Tsai, S. N. Manjunatha, Sheng Hsiung Chang, Ming-Jer Jeng, Liann-Be Chang, Chun-Huan Chang, Mukta Sharma, Chi-Tsu Yuan

Summary: The surface morphologies, light harvesting abilities, crystal structures, and excitonic properties of FAPbI(3) based alloy perovskite thin films were investigated. Different alloy compositions resulted in varying crystal structures and photovoltaic responses. The Cs(x)FA(1-x)PbI(3) solar cells showed better photovoltaic responses due to their unique surface morphology and long carrier lifetime.

PROCESSES (2023)

Article Chemistry, Physical

Ladder-type dihydronaphtho[1,2,3,4-rst]pentaphene as building block to construct hole-transporting materials for perovskite solar cells

Dharuman Chandrasekaran, Shin-Jyun Liou, Wei-Hao Chiu, Lee-Che Lee, Kun-Mu Lee, Yi-Chen Wu, Hsien-Hsin Chou, Yuan Jay Chang, Yung-Sheng Yen

Summary: This study synthesized three D-7C-D type PAHs-based hole-transporting materials (HTMs) and demonstrated their efficiency in perovskite solar cells (PSCs). The PSC devices fabricated with one of the compounds, DC-1, achieved a highly efficient power conversion efficiency (PCE) of 18.09%, outperforming the devices based on DC-2 and DC-3, and slightly higher than those using the control material spiro-OMeTAD. These novel D-7C-D molecules show promising performance as HTMs for PSCs and contribute to the development of high-efficiency perovskite solar cells.

JOURNAL OF POWER SOURCES (2023)

Article Engineering, Electrical & Electronic

Modulating incident light for improved CO2 photoreduction in freestanding silver bismuth iodide/nanocellulose films with exotic gold nanoparticles

Ming-Chung Wu, Yin-Hsuan Chang, Yi-Jing Lu, Kai-Chi Hsiao, Ting-Han Lin, Jin-Mao Chang, Kai-Hsiang Hsu, Jen-Fu Hsu, Kun-Mu Lee

Summary: Researchers have explored the conversion of CO2 into carbon-based fuels through photocatalytic reactions. They fabricated a novel freestanding photocatalyst composite film by immobilizing Ag3BiI6 onto a nanocellulose transparent film. The resulting film exhibited high photocatalytic activity and stability for CO2 reduction.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2023)

Article Nanoscience & Nanotechnology

Effects of bendable P3CT polymers layer on the photovoltaic performance of perovskite solar cells

Anjali Chandel, Shou-En Chiang, Wen-Hsin Chang, Jia-Ren Wu, Chi-Tsu Yuan, Sheng Hsiung Chang

Summary: We report on the formation of a bendable and edge-on poly[3-(4-carboxybutyl)thiophene-2,5-diyl] (P3CT) polymer thin layer used as a hole modification layer (HML) in inverted perovskite solar cells. The aggregations of 2D layer-like P3CT polymers in DMF solution can be formed through aromatic π-π stacking interactions and/or hydrogen-bonding interactions. These highly influence the photovoltaic performance of the inverted perovskite solar cells. The P3CT polymers modify the surface properties of the transparent conductive substrate, dominate the formation of perovskite crystalline thin films, and play important roles in the efficient and stable perovskite solar cells.

NANOTECHNOLOGY (2023)

Editorial Material Nanoscience & Nanotechnology

Editorial for focus on manipulations of atomic and molecular layers and its applications in energy, environment sciences and optoelectronic devices

Sheng Hsiung Chang, Xiangbo Meng, Jian Liu, Dung-Sheng Tsai, Xinwei Wang, Chiashain Chuang, Cheng-Ying Chen, Aidong Li

Summary: This Focus highlights the significance of manipulating atomic and molecular layers for various applications. It features 15 original research papers that showcase the applications of techniques such as atomic layer deposition, chemical vapor deposition, and wet chemistry in manipulating atomic and molecular layers in areas such as lithium-ion batteries, supercapacitors, catalysis, field-effect transistors, and optoelectronics.

NANOTECHNOLOGY (2023)

Article Materials Science, Multidisciplinary

Enhancing efficiency and stability of perovskite solar cells through two-step deposition method with the addition of cesium halides to PbI2 precursor

Seoungjun Ahn, Wei-Hao Chiu, Hsin-Ming Cheng, Vembu Suryanarayanan, Gao Chen, Yu-Ching Huang, Ming-Chung Wu, Kun-Mu Lee

Summary: Cesium halides, such as CsCl, CsBr, and CsI, were introduced as a modulator in the precursor of perovskite films to manipulate their crystallization. The addition of CsI resulted in dense homogeneous perovskite films with high crystallinity, preferential orientation, and a pure black perovskite phase. The carrier lifetime of the perovskite films was significantly increased, leading to an improvement in the power conversion efficiency (PCE) of the small-area devices from 17.45% to 20.29%. The devices also exhibited excellent stability, maintaining 75% of the initial PCE after 350 hours of continuous irradiation. This study demonstrates the reliable application of CsI regulation for preparing high-performance perovskite solar cells.

ORGANIC ELECTRONICS (2023)

Article Chemistry, Multidisciplinary

Effects of drying time on the formation of merged and soft MAPbI3 grains and their photovoltaic responses

Anjali Chandel, Qi Bin Ke, Shou-En Chiang, Hsin-Ming Cheng, Sheng Hsiung Chang

Summary: Manipulating the grain sizes of soft CH3NH3PbI3 (MAPbI(3)) thin films and the atomic contact strength at the MAPbI(3)/P3CT-Na interface through variations in drying time of precursor solutions has significant effects on the performance and lifespan of inverted perovskite photovoltaic cells. The increased short-circuit current density (J(SC)) and fill factor (FF) can be attributed to the formation of merged MAPbI(3) grains. Additionally, the encapsulated photovoltaic cells exhibit higher open-circuit voltage (V-OC) and power conversion efficiency due to the increased carrier density of the MAPbI(3) crystalline thin film.

NANOSCALE ADVANCES (2023)

Article Thermodynamics

Thermal properties of clay containing polymeric reinforcement as an eco-friendly bio-insulation composite for buildings

Souad Ghyati, Said Kassou, Mostapha El Jai, El Hassan El Kinani, Mabrouk Benhamou, Sheng Hsiung Chang

Summary: Polymer/clay-based composites were prepared using natural clay and PEG4000 as the dispersed phase, and the effect of PEG content on surface morphology, thermal stability, and thermophysical properties was studied. The incorporation of PEG chains improved thermal characteristics and insulation properties, making the composite a good thermal insulator for polymer contents higher than 2.5%. The resulting composite not only showed interesting insulation characteristics but also met economic and environmental requirements.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY (2022)

Article Energy & Fuels

Highly efficient double-side-passivated perovskite solar cells for reduced degradation and low photovoltage loss

Shahriyar Safat Dipta, Md Habibur Rahaman, Walia Binte Tarique, Ashraful Hossain Howlader, Ayush Pratik, John A. Stride, Ashraf Uddin

Summary: Implementing a double-sided passivation approach can enhance the performance of n-i-p structured PSCs and improve the stability and photovoltaic properties of the cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Paste-based silver reduction for iTOPCon rear side metallization

Daniel Ourinson, Andreas Brand, Andreas Lorenz, Marwan Dhamrin, Sebastian Tepner, Michael Linse, Nathalie Goettlicher, Kosuke Tsuji, Jonas D. Huyeng, Florian Clement

Summary: This work presents two approaches to reduce the amount of silver on the rear side of M2-sized industrial iTOPCon solar cells. The Cu-based approach shows promise with similar power conversion efficiency compared to the conventional approach, while the Al-based approach exhibits some limitations but demonstrates the potential of such type of contact for iTOPCon solar cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Screen printable copper pastes for silicon solar cells

Abasifreke Ebong, Donald Intal, Sandra Huneycutt, Thad Druffel, Ruvini Dharmadasa, Kevin Elmer, Apolo Nambo

Summary: This study demonstrates the successful metallization of a PERC silicon solar cell using screen-printable copper (Cu) paste. The Cu paste contains antioxidant additives and diffusion inhibitors to prevent oxidation and diffusion of Cu. The Cu-printed cells achieved an efficiency of 19% and showed no Cu diffusion after characterization tests. The long-term stability and effectiveness of the Cu diffusion barrier were also confirmed.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Defining specifications for accurate Metal/TCO specific contact resistivity measurements by TLM in silicon heterojunction devices

Senami Zogbo, Wilfried Favre, Olivier Bonino, Marie-Estelle Gueunier-Farret

Summary: Measuring specific contact resistivity (pc) is crucial for interface engineering in high efficiency solar cells. The Transfer Length Method (TLM) is commonly used for evaluating layer sheet resistance (Rsheet) and pc, but it is not suitable for metal/Transparent Conductive Oxide (TCO) interface evaluation in silicon heterojunction (SHJ) cells. This study investigates the parameters that restrict current confinement within the TCO, including mid-gap trap density (Dit) at the a-Si:H/c-Si interface and the activation energy (Ea = Ec - EF) variation of a-Si:H contact layers.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules part I: Cell-ribbon mechanical interaction through the solder

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: The phenomenon of ribbon lengthening in PV modules exposed to thermal cycling is not well explained in the literature. In this study, a three layers model is proposed to explain this effect, and the predictions of the model are validated through finite element method simulations and experiments. The results show that the model predictions are consistent with the indirect measurements, but not with the direct measurements. Additionally, it is inferred that the encapsulant plays a role after the solder failure.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules, Part II: Glass-ribbon mechanical interaction through the encapsulant

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: This study investigates the problematic ribbon lengthening observed in PV modules exposed to high amplitude thermal cycling. A simplified system model is proposed and accurate predictions are obtained using the Finite Element Method. The results show that the thickness of the encapsulant has a substantial impact on the lengthening of the ribbons.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Gallium nanoparticles as antireflection structures on III-V solar cells

S. Catalan-Gomez, E. Martinez Castellano, M. Schwarz, M. Montes Bajo, L. Dorado Vargas, A. Gonzalo, A. Redondo-Cubero, A. Gallego Carro, A. Hierro, J. M. Ulloa

Summary: This study investigates the use of core-shell gallium nanoparticles as functional light scatterers on solar cells. By optimizing the nanoparticle size, the short-circuit current of the solar cells is significantly improved. The underlying physical mechanism is studied through optical measurements and simulations, and a method to reduce the plasmonic effect of the nanoparticles is demonstrated.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Highly reflective and passivated ohmic contacts in p-Ge by laser processing of aSiCx:H(i)/Al2O3/aSiC films for thermophotovoltaic applications

M. Gamel, G. Lopez, A. M. Medrano, A. Jimenez, A. Datas, M. Garin, I. Martin

Summary: In this study, a highly reflective ohmic contact to p-type c-Ge material is demonstrated, which can improve the efficiency of thermophotovoltaic devices. The experimental results show that this contact can simultaneously meet the requirements of good back surface passivation, low electrical resistivity, and high reflectivity. Moreover, simulations suggest that implementing these back contacts has the potential to achieve conversion efficiencies comparable to high-efficiency c-Ge TPV cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Improvement on solar selective absorption properties of anodic aluminum oxide photonic crystal films by electrodeposition of silver

Hongyang Wei, Qing Xu, Dongchu Chen, Min Chen, Menglei Chang, Xiufang Ye

Summary: This study prepared solar selective absorption films based on anodic aluminum oxide (AAO) photonic crystals using a unique electrodeposition method. The Co-Ag electrodeposited film exhibited superior solar selective absorption properties and thermal stability.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Optical absorption driven by efficient refraction and light concentration for photovoltaic applications

Ankit Kumar, Ankit Chauhan, Jordi Llobet, Helder Fonseca, Patricia C. Sousa, Carlos Calaza, Gil Shalev

Summary: This study found that decorating subwavelength arrays with SiO2 quasi-nanolenses (qNL arrays) can enhance the absorption of the solar spectrum. Optical absorption mechanisms in qNL arrays were investigated using near-field scanning optical microscopy (NSOM), revealing that the enhancement is a result of the combination of effective antireflection coating, increased optical interactions between adjacent dielectrics for elevated light trapping, and strong light concentration due to the presence of qNLs.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Progress on the reduction of silver consumption in metallization of silicon heterojunction solar cells

S. Pingel, T. Wenzel, N. Goettlicher, M. Linse, L. Folcarelli, J. Schube, S. Hoffmann, S. Tepner, Y. C. Lau, J. Huyeng, A. Lorenz, F. Clement

Summary: This study demonstrates the potential to reduce silver consumption in highly efficient SHJ cells through fine-line screen printing using low temperature paste with various screens. The results show that using finer mesh allows for narrower grid fingers and lower resistance, leading to improved cell efficiency. Simulation results indicate that module wire configuration is crucial for reducing silver consumption.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Efficient-thermal conductivity, storage and application of bionic tree-ring composite phase change materials based on freeze casting

Xibo He, Jun Qiu, Wei Wang, Yicheng Hou, Yong Shuai

Summary: This paper proposes a novel phase change material with high thermal conductivity and stability for fast photo-thermal conversion and storage. The experimental results demonstrate excellent durability and stability of the phase change material, with good performance in thermal conductivity and thermal storage efficiency.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Solar evaporation of liquid marbles with tunable nanowire array

Qingyuan Liu, Lin Wang, Zheng Liu, Guohua Liu

Summary: A new evaporating structure consisting of liquid marble with tunable nanowire array is proposed to enhance solar evaporation. The experiments show that the liquid marble with nanowire array exhibits outstanding evaporation performance, which has significant implications for seawater desalination or wastewater treatment.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Effects of different interface on the stability of hybrid heterojunction solar cells

Hao Liu, Qiming Liu, Jinpei Liu, Yonggang Zhao, Yingjie Yu, Yue An, Ganghui Wei, Yanzheng Li, Yujun Fu, Junshuai Li, Deyan He

Summary: Moisture in the air is identified as the main cause of performance degradation in organic-inorganic hybrid solar cells. Exposure to air leads to the growth of thin oxide layer on the interface and the formation of silver sulfide, increasing the series resistance and decreasing the fill factor, thus degrading the cell performance.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Refractive indices and extinction coefficients of p-type doped Germanium wafers for photovoltaic and thermophotovoltaic devices

E. Blanco, P. Martin, M. Dominguez, P. Fernandez-Palacios, I. Lombardero, C. Sanchez-Perez, I. Garcia, C. Algora, M. Gabas

Summary: This study addresses the lack of optical parameters for p-type Ge wafers by determining the complex refractive indices of commercial Ge wafers with varying doping levels. The obtained data successfully reproduces the critical points associated with interband transitions and absorption features below the bandgap. The refractive indices were validated through experimental measurements and solar cell simulations.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)