期刊
SOFT MATTER
卷 11, 期 22, 页码 4481-4486出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sm00298b
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资金
- National Natural Science Foundation of China [21071124, 21173189]
- Zhejiang Provincial Natural Science Foundation of China [LY14B030005]
- Foundation of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University [2016-03]
A series of reversible phase transformation ammonium- and phosphonium-based polyoxometalate ionic liquid (POM-IL) gels were synthesized and studied with a focus on the correlation between their physicochemical properties and their chemical structure. The products were successfully characterized by IR, UV, XRD and TG-DTA, and their ionic conductivities were measured. The Keggin-type heteropolyanion clusters decorated with long alkyl chains demonstrated a tendency to exhibit a gel state at room temperature, while all the gels transformed into liquids after heating and then recovered after cooling. With a decrease in the alkyl chain length, a significant improvement in the thermal stability and conductivity of the ammonium-based POM-IL gels can be achieved. Moreover, compared with the corresponding ammonium compound, phosphonium-based POM-IL gel was found to be more stable at high temperature and exhibited better conductivity.
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