4.6 Article

Induced polar order in sedimentation equilibrium of rod-like nanoswimmers

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SOFT MATTER
卷 11, 期 12, 页码 2416-2422

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sm02701a

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  1. Ministry of Science and Technology of Taiwan

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The active diffusion and sedimentation equilibrium of rod-like nanoswimmers with length L are investigated by dissipative particle dynamics. In the absence of propulsion, the nanorod has the rotational correlation time tau(theta) and mobility mu(0), which vary with L. On the basis of the mean squared displacement, the diffusive behavior of rod-like nanoswimmers subject to active force Fa is found to follow (D - D-0) proportional to (mu F-0(a)) (2)tau(theta), where D-0 depicts the Brownian diffusivity. When the nanoswimmer suspension is under the external force F-e, the balance between the downward migration and upward active diffusion yields the sedimentation length delta = D/(mu F-0(e)), which no longer obeys delta(0) = k(B)T/F-e obtained from the Einstein-Smoluchowski relationship, D-0 = mu(0)k(B)T. Different from the suspension of passive rods, the polar order is clearly seen for active rods. The local polar order is essentially constant within the distance of about 2 delta from the bottom wall but decays as the distance is further increased. In this work, the active Peclet number is small compared to unity and the maximum polar order grows linearly with F-e/F-a. The polar order arises because it is easier for the nanoswimmer with the swimming direction opposite to the external force to escape from the bottom wall.

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