Elucidation of the Fe(iv)=O intermediate in the catalytic cycle of the halogenase SyrB2

Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates

(2013) K. Park et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Novel approaches for the accumulation of oxygenated intermediates to multi-millimolar concentrations

(2012) Carsten Krebs et al.   COORDINATION CHEMISTRY REVIEWS

Structural and Spectroscopic Properties of the Peroxodiferric Intermediate of Ricinus communis Soluble Δ9 Desaturase

(2012) Martin Srnec et al.   INORGANIC CHEMISTRY

 -Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity

(2012) M. Srnec et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Nuclear Resonance Vibrational Spectroscopy on the FeIVO S=2 Non-Heme Site in TMG3tren: Experimentally Calibrated Insights into Reactivity

(2011) Shaun D. Wong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence for a High-Spin Fe(IV) Species in the Catalytic Cycle of a Bacterial Phenylalanine Hydroxylase

(2011) Aram Joel Panay et al.   BIOCHEMISTRY

Activation of α-Keto Acid-Dependent Dioxygenases: Application of an {FeNO}7/{FeO2}8Methodology for Characterizing the Initial Steps of O2Activation

(2011) Adrienne R. Diebold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Selective Halogenation by SyrB2: A Computational Study

(2010) Tomasz Borowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Does the TauD Enzyme Always Hydroxylate Alkanes, While an Analogous Synthetic Non-Heme Reagent Always Desaturates Them?

(2010) Dandamudi Usharani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substrate-Triggered Formation and Remarkable Stability of the C−H Bond-Cleaving Chloroferryl Intermediate in the Aliphatic Halogenase, SyrB2

(2009) Megan L. Matthews et al.   BIOCHEMISTRY

First-Principles Study of Non-heme Fe(II) Halogenase SyrB2 Reactivity

(2009) Heather J. Kulik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substrate positioning controls the partition between halogenation and hydroxylation in the aliphatic halogenase, SyrB2

(2009) M. L. Matthews et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Combined NRVS and DFT Study of FeIVO Model Complexes: A Diagnostic Method for the Elucidation of Non-Heme Iron Enzyme Intermediates

(2008) Caleb B. Bell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon Dioxide: A Waste Product in the Catalytic Cycle of α-Ketoglutarate Dependent Halogenases Prevents the Formation of Hydroxylated By-Products

(2008) Sam P. de Visser et al.   JOURNAL OF PHYSICAL CHEMISTRY B