4.6 Article

A hierarchical hybrid design for high performance tin based Li-ion battery anodes

期刊

NANOTECHNOLOGY
卷 24, 期 20, 页码 -

出版社

IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/24/20/205401

关键词

-

资金

  1. Starting Foundation for New Teacher of Shanghai Jiao Tong University [12X100040119]
  2. Shanghai Municipal Natural Science Foundation [12ZR1414300]
  3. Third Phase of 211 Project for Advanced Materials Science [WS3116205007]

向作者/读者索取更多资源

Novel hierarchical hybrids, tin dioxide@carbon hollow spheres with encapsulated tin nanoparticles (SnO2@HCS@Sn), were fabricated by combining solution and vapor phase techniques. The phase composition, morphological evolution and porosity of the hierarchical hybrids were characterized by x-ray diffraction, energy dispersive x-ray spectroscopy, scanning and transmission electron microscopy, and N-2 adsorption-desorption analysis. The significantly improved electrochemical performance of this functional material is attributed to its heterogeneous architecture which unifies hollow carbon spheres with tin nanoparticles with a diameter of less than 20 nm, which are further conformally covered by ultra-small tin dioxide nanoplates. The ultrathin SnO2 nanoplates grown on the carbon spheres effectively increase the charge-transfer properties and shorten the transport lengths for both electrons and lithium ions. The mesoporous carbon spheres offer excellent conductivity and abundant void space to buffer the large volume change during cycling. High initial capacity (similar to 1766 mAh g(-1) at 0.1 Ag-1), high initial Coulombic efficiency (56.4%), and long cycle life (100 cycles with similar to 710 mAh g(-1)) have been realized in the hierarchical hybrid tin-based anodes.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Engineering, Mechanical

Effect of Cu on the Tribocorrosion Behavior of Antibacterial CoCrMo Alloys in Simulated Biological Environment

Xuefeng Song, Ying Liu, Xiaoyan Wang, Erlin Zhang

Summary: The addition of copper element reduces the corrosion resistance and wear resistance of Co-based alloy, while the solution containing 10% fetal bovine serum exhibits lubrication function. The tribocorrosion behavior of CoCrMo and CoCrMo-Cu alloy is mainly controlled by mechanical wear.

JOURNAL OF TRIBOLOGY-TRANSACTIONS OF THE ASME (2021)

Article Materials Science, Ceramics

Metal organic framework derived Ni/CeO2 catalyst with highly dispersed ultra-fine Ni nanoparticles: Impregnation synthesis and the application in CO2 methanation

Xiaoqian Feng, Kun Wang, Mingxian Zhou, Feng Li, Jing Liu, Min Zhao, Liping Zhao, Xuefeng Song, Peng Zhang, Lian Gao

Summary: This work successfully addressed the issue of nanocrystal coarsening in traditional metal/support structures by designing and synthesizing a novel Ni/CeO2 catalyst. The catalyst with ultrafine Ni nanoparticles exhibited high dispersion and good thermostability, showing excellent catalytic performance. This study provides a facile method for synthesizing nanocomposite catalysts with high catalytic activity and stability for various applications.

CERAMICS INTERNATIONAL (2021)

Article Chemistry, Inorganic & Nuclear

A Wet Impregnation Strategy for Advanced FeNi-based Electrocatalysts towards Oxygen Evolution

Xueyang Wang, Yuanjun Liu, Tiange Wei, Jinyong Sun, Xuefeng Song, Peng Chen, Jinghui He, Xiaoping Shen, Guoxing Zhu

Summary: The study utilized typical wet impregnation method to prepare advanced electrocatalysts for oxygen evolution reaction, achieving catalytic performance close to or better than benchmarked RuO2 and IrO2 catalysts with good catalytic stability. The non-chemical synthesis route presented a new strategy for advanced oxygen evolution catalysts.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2021)

Article Nanoscience & Nanotechnology

Coating of Phosphide Catalysts on p-Silicon by a Necking Strategy for Improved Photoelectrochemical Characteristics in Alkaline Media

Feng Li, Yanqi Yuan, Xiaoqian Feng, Jing Liu, Sheng Chen, Yue Lin, Yanting Sun, Han Chen, Liping Zhao, Xuefeng Song, Peng Zhang, Lian Gao

Summary: The methodology of coating electrocatalysts on semiconductor substrates is critical for the catalytic performance of photoelectrochemical electrodes. The formation of a TiO2 necking layer between catalyst particles and substrates plays a key role in ensuring surface catalytic activity and durability. This coating strategy provides a practical approach to meet commercial requirements for low-cost, highly efficient, and durable photoelectrodes.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

A robust, hydrophobic CeO2/NiCoCrAlY composite coating with excellent thermal stability and corrosion resistance prepared by air plasma spray

Lingyue Hu, Xuefeng Song, Xiaofeng Zhao, Fangwei Guo, Fan Yang, Ping Xiao

Summary: The CeO2/NiCoCrAlY composite coating exhibits superior wear resistance, excellent high-temperature stability, high bonding strength, and good corrosion resistance, while maintaining hydrophobicity even after abrasion or annealing. It provides a reliable and effective route for fabricating hydrophobic surfaces with potential applications in harsh environments.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Engineering, Environmental

Attapulgite modulated thorny nickel nanowires/graphene aerogel with excellent electromagnetic wave absorption performance

Fei Sun, Qingdong Liu, Yifeng Xu, Xipeng Xin, Zezhen Wang, Xuefeng Song, Xiaofeng Zhao, Jijin Xu, Jing Liu, Liping Zhao, Peng Zhang, Lian Gao

Summary: The study focuses on developing electromagnetic wave absorption materials (EAMs) to mitigate the harm caused by the extensive use of electromagnetic waves. A novel attapulgite-modulated thorny nickel nanowires/graphene aerogel was fabricated with excellent absorption performance through a simple manufacturing process.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Enhancing the Long-Term Photoelectrochemical Performance of TiO2/Si Photocathodes by Coating of Ti-Doped Mesoporous Hematite

Feng Li, Wangshu Zheng, Jing Liu, Liping Zhao, Djordje Janackovic, Yu Qiu, Xuefeng Song, Peng Zhang, Lian Gao

Summary: In this study, Ti-doped hematite with ordered mesoporous structure was synthesized and coated on TiO2-protected silicon, significantly enhancing the photoelectrochemical performance. Ti doping led to a more uniform dispersion of photoelectrons on the surface, while the low electronic concentration in the TiO2 layer prolonged the device lifetime. This research provides an effective protection mechanism for composite photoelectrodes, offering a promising strategy for protecting the photocathode through surface decoration with carefully tailored catalysts.

ACS APPLIED ENERGY MATERIALS (2021)

Article Zoology

Transcriptome analysis of Macrobrachium rosenbergii: Identification of precocious puberty and slow-growing information

Na Ying, Yuan Wang, Xuefeng Song, Bo Qin, Yanqing Wu, Liguo Yang, Wenhong Fang

Summary: This study utilized transcriptome sequencing technology to investigate the precocious puberty and growth retardation disease in M. rosenbergii, identifying significantly expressed genes and enriched pathways, and validating the accuracy of the data. This provides key insights into the genetic markers of this disease.

JOURNAL OF INVERTEBRATE PATHOLOGY (2022)

Article Chemistry, Multidisciplinary

Covalently Assembled Black Phosphorus/Conductive C3N4 Hybrid Material for Flexible Supercapacitors Exhibiting a Superlong 30,000 Cycle Durability

Xipeng Xin, Yifeng Xu, Hexige Wuliji, Fei Sun, Qingdong Liu, Zezhen Wang, Tian-ran Wei, Xiaofeng Zhao, Xuefeng Song, Lian Gao

Summary: A chemically bridged BP/conductive g-C3N4 hybrid was developed through a ball-milling method to address the low electrical conductivity and poor structure stability of BP. The hybrid material exhibited higher electrical conductivity and improved cycling stability, making it a promising electrode material for high-performance supercapacitors.

ACS NANO (2022)

Article Fisheries

Report of Amyloodinium ocellatum in farmed black scraper (Thamnaconus modestus) in China

Na Ying, Yuan Wang, Bo Qin, Huijuan Chen, Xuefeng Song, Liguo Yang, Yanqing Wu, Wenhong Fang

Summary: Black scraper, Thamnaconus modestus, a filefish with high market value, has seen decreased stock due to overexploitation and environmental fluctuations. Industrial culture has alleviated supply-demand tension but also led to disease outbreaks, as seen in a mass death case in China caused by Amyloodinium ocellatum. Observations suggest the need for increased surveillance to prevent mass fish mortality.

AQUACULTURE (2022)

Article Engineering, Electrical & Electronic

Low RCS, Broadband Polarization Conversion Metasurface Antenna Based on Reactance Loading

Meng Guo, Wei Wang, Fang Hao, Ping Huang, Linshu Gong, Xuefeng Song

Summary: This paper presents a reactance-loaded polarization conversion metasurface (PCMS) for a metasurface antenna (MTA) with low radar cross section (RCS) and broadband radiation. By integrating a metallic surface with open and closed slits into the PCMS, reactance features are introduced to modulate the near-field interactions and expand the polarization conversion bandwidth. The reactance-loaded metallic surface, combined with a grounded substrate, forms a broadband metasurface radiator.

IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION (2022)

Article Engineering, Electrical & Electronic

Compact Broadband Linearly Polarized Quincunx Metasurface Antennas Using Embedded Fractal Design

Meng Guo, Wei Wang, Fang Hao, Ping Huang, Linshu Gong, Xuefeng Song

Summary: This article presents a quincunx metasurface structure that is used to design compact broadband metasurface antennas. The structure consists of five interconnected squares arranged in a quincunx pattern. The spacing between adjacent units is increased, increasing the edge capacitance. The surface current is also adjusted to flow along the diagonal of the quincunx patches, resulting in a large strip inductance. This allows the resonance frequency to be shifted to lower frequencies, while maintaining a compact radiating aperture.

IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION (2023)

Article Engineering, Multidisciplinary

BiScO3-PbTiO3 nanofibers piezoelectric sensor for high-temperature pressure and vibration measurements

Yi Xin, Hongyan Liu, Meng Cui, Xuefeng Song, Yuhang Wang, Tingting Lin, Lingling Wang, Gang Wang

Summary: In this study, pure phase BS-PT nanofibers were successfully synthesized by optimizing the concentration of the electrospinning additive and the sintering temperature. The BS-PT nanofiber piezoelectric sensor showed a stable sensitivity above 4 V/N in the temperature range of 60-200 degrees C and at frequencies of 10-40 Hz. Furthermore, the sensor exhibited a nearly linear output voltage with increasing excitation pressure in the range of 0.07 N to 0.55 N at temperatures of 160-260 degrees C, and the sensitivity at 220 degrees C was still higher than 5.4 V/N. These findings suggest that the BS-PT nanofiber piezoelectric sensor holds great promise for high-temperature pressure and vibration measurements.

MEASUREMENT (2023)

Article Materials Science, Ceramics

High-performance Cu2O-based photocatalysts enabled by self-curling nanocelluloses via a freeze-drying route

Zezhen Wang, Xipeng Xin, Yifeng Xu, Qingdong Liu, Yiqiu Zhu, Xuefeng Song, Zhen Liu, Jijin Xu, Jing Liu, Lian Gao

Summary: Cu2O/C composite aerogel, synthesized through freeze-drying and calcination, exhibits hollow carbon microfibers anchored with Cu2O nanocubes. The resulting Cu2O/C composite aerogel shows significantly enhanced photodegradation efficiency of tetracycline under visible-light irradiation, reaching 97.3% in 120 min and maintaining a cycling photodegradation rate of 84.3% after 10 cycles. These findings provide remarkable strategies for designing and constructing Cu2O-based photocatalysts for practical photodegradation of tetracycline under visible-light exposure.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Article Fisheries

Transcriptome Analysis of Greenfin Horse-Faced Filefish (Thamnaconus septentrionalis) Gills in Response to Amyloodinium ocellatum (AO) Infection

Li-Guo Yang, Yue Wang, Wen-Bin Xu, Bo Qin, Na Ying, Xue-Feng Song, Yan-Feng Yue, Xiao-Shan Wang, Bian-Bian Zhang, Yan-Qing Wu

Summary: This study used an RNA-seq approach to analyze the differential gene expression in the greenfin horse-faced filefish infected with Amyloodinium ocellatum. The results revealed several genes associated with the infection, and GO and KEGG analyses showed enrichment in signaling pathways related to viral protein interaction with cytokines. This transcriptomic study provides new molecular insights into the pathology caused by AO infestation and offers alternative theories for future research on controlling and managing AO.

FISHES (2022)

暂无数据