期刊
NANOTECHNOLOGY
卷 20, 期 14, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/20/14/145502
关键词
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资金
- National Natural Science Foundation of China [20602015, 20772038]
- Hubei Province [2007ABB017]
- Program for Chenguang Young Scientist for Wuhan [200750731283]
Cysteine modified Ag nanoparticles were prepared in aqueous solution, via one-pot protocol, which were characterized by transmission electron microscopy ( TEM), Fourier transform infrared (FT-IR) and ultraviolet-visible spectroscopy (UV-vis). The nanoparticles provided a simple and rapid strategy to detect histidine (His) visually with the help of Hg2+ ions in solution. The colorimetric sensor allows a rapidly quantitative assay of histidine down to the concentration of 3 x 10(-5) M. The mechanism by which Hg2+ ions can bind with both the cysteine modified Ag nanoparticles and His molecule through cooperative metal-ligand interactions is discussed.
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