4.8 Article

Carbon dot-based white and yellow electroluminescent light emitting diodes with a record-breaking brightness

期刊

NANOSCALE
卷 10, 期 23, 页码 11211-11221

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nr01834k

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资金

  1. National Natural Science Foundation of China [U1710117, U1610255, U1607120, 61705156]
  2. Shanxi Provincial Key Innovative Research Team in Science and Technology [2015013002-10, 201605D131045-10]
  3. Shanxi Provincial Key Research and Development Program [201603D111010, 201703D321015-1]
  4. Shanxi Province Natural Science Foundation [201601D021018]
  5. Shanxi University Scientific and Technical Innovation Project [2016135]

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First, oleophilic carbon dots (CDs) with a fluorescence quantum yield (QY) of 41% were synthesized by a one-pot microwave-assisted carbonization method. Then, CD-based electroluminescent light emitting diodes (CD-LEDs) were prepared. The impact of CD aggregation on the brightness of CD-LEDs was studied. The results show that, to some extent, with the decrease of the aggregation of the CD film, the luminescence quenching of the CD-LEDs gradually decreased, and the luminance of the CD-LEDs gradually increased. Hence, in order to improve the dispersion of CDs and reduce the aggregation of CDs and the luminescence quenching of the devices, host-guest doping was adopted to effectively improve the brightness of CD-LEDs. In this work, the yellow emission of the doped devices is mainly derived from the direct carrier trapping on CDs. Moreover, white and yellow CD-LEDs were obtained from the same oleophilic CDs by tuning the structure of the devices. The white CD-LEDs exhibit a high color rendering index (CRI) of 83 with a luminance of 455.2 cd m(-2). The yellow CD-LEDs show the maximum brightness of 339.5 cd m(-2) and excellent color stability. The results show that the luminescence quenching of CD-LEDs was resisted and the brightness of CD-LEDs was improved by using host-guest doping.

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