期刊
NANOSCALE
卷 6, 期 11, 页码 5714-5717出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr00658e
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资金
- National Basic Research Program of China [2013CB934302]
- Natural Science Foundation of China [21222301, 21171170]
- Ministry of Human Resources and Social Security of China
- Chinese Academy of Sciences
An active, recoverable, and recyclable nanocluster catalyst, Au-25(SR)(18)(-), has been developed to catalyze the formation of alpha,beta-unsaturated ketones or aldehydes from propargylic acetates. The catalytic process has been proposed to be initialized by an S(N)2' addition of OH-. Moreover, a dramatic solvent effect was observed, for which a rational explanation was provided.
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