Perpendicular orientation of sub-10 nm channels in polystyrene-b-poly(4-hydroxyl styrene)/PEG oligomer blend thin films

Vertically oriented cylinders via the directional coalescence of the spheres embedded in the blend thin films frompolystyrene-b-poly(4-hydroxyl styrene) (PS-b-PHS) and PEG induced by solvent annealing were achieved. Removal of PEG water led to the formation of nanochannels throughout the films. The diameter of these channels could be as small as 9 nm which might enhance the applicability of the nano-porous films as size-selective membranes and controllable drug delivery systems for the objects less than 10 nm.