Article
Multidisciplinary Sciences
Hui Zhang, Tao Xu, Kaihao Yu, Wen Wang, Longbing He, Litao Sun
Summary: Atomic diffusion is a powerful tool for the synthesis of heterostructures, but controlled atomic diffusion remains challenging. In this study, the authors demonstrate controlled solid-solid atomic diffusion between Ag nanowires and Te nanowires to produce 1D heterostructures by applying an electrical bias inside a TEM.
NATURE COMMUNICATIONS
(2021)
Review
Polymer Science
Ottavia Bellotto, Maria C. Cringoli, Siglinda Perathoner, Paolo Fornasiero, Silvia Marchesan
Summary: The use of peptides as templates for inorganic nanoparticle formation is an environmentally friendly method with applications in various fields. Short-peptide gelators provide dynamic supramolecular environments, and recent research progress outlines future research directions.
Article
Chemistry, Physical
Roberto Luigi Oliveri, Bernardo Patella, Floriana Di Pisa, Alfonso Mangione, Giuseppe Aiello, Rosalinda Inguanta
Summary: This study reported the preliminary results of manufacturing CuZnSnSe (CZTSe) and CuInGaSe (CIGS) nanowire arrays through one-step electrodeposition for potential p-n junction fabrication, which involved morphology optimization and electrochemical parameter optimization. The samples were characterized using various techniques, demonstrating the fabrication of nanostructures with an average diameter of approximately 230 nm and length of around 3 μm.
Article
Chemistry, Physical
Xuefei Li, Zhenfei Jiang, Feiyue Ge, Chen-Lei Tao, Wenjie Gu, Dan Xu, Feifan Chen, Zhuoyi Xie, Fang Cheng, Xue-Jun Wu
Summary: 1D/2D heterostructures allow for the combination of different dimensionalities into one system, but effective strategies for integrating these components are lacking. This study presents a general seeded growth method for constructing epitaxial 1D/2D heterostructures with various compositional combinations, expanding the variety and architecture of available heterostructures and providing a toolbox for exploring their promising applications.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jiawen Cao, Pu Ouyang, Suhua Yu, Feng Shi, Chuanli Ren, Chengyin Wang, Ming Shen, Zhanjun Yang
Summary: An effective electrochemical immunosensor was developed for detecting liver cancer biomarkers using hedgehog-like Bi2S3 nanostructures, synthesized with a novel CTAB-trimellitic acid composite soft template and thiourea as the sulfur source. The sensor showed significantly improved sensitivity and expanded linear range, and can be applied to detect cancer biomarkers in clinical serum samples.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Junli Liu, Mingxin Wang, Maria C. Dipalo, Jing Zhuang, Wenxiong Shi, Xun Wang
Summary: The study successfully prepared CuO-PMA-Ag sub-1 nm nanosheet heterostructures with excellent catalytic activity, paving the way for the synthesis and broader applications of multi-component 2D hybrid sub-1 nm heterostructures.
Review
Chemistry, Multidisciplinary
Ying-Li Shi, Xue-Dong Wang
Summary: 1D organic micro/nanostructures (OMNSs) based on pi-conjugated molecules are ideal candidates as photonic units due to their unique photophysical advantages. Although they have broad application prospects in photonics devices, huge challenges remain before they can be actually used as components of optical circuits in photonics chips.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Bernardo Patella, Salvatore Piazza, Carmelo Sunseri, Rosalinda Inguanta
Summary: Anodic alumina membranes with a high degree of porous structure are ideal templates for manufacturing nanostructured materials in optoelectronics, sensors, magnetic memories, and electronic circuits. By adjusting anodizing parameters, the morphology characteristics such as pore length, pore diameter, and cell density can be accurately controlled. The addition of aluminum ions to phosphoric acid-based anodizing solution can significantly affect the morphology of the porous layer in anodic alumina membranes, impacting the overall structure and properties.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Physical
Caroline Fradin, Francois Orange, Sonia Amigoni, Caroline R. Szczepanski, Frederic Guittard, Thierry Darmanin
Summary: This study proposes a method of soft templating using self-assembly of conducting monomers in organic solvents to form porous nanotubular structures. Results show that NaphDOT is capable of forming vertically aligned nanotubes, and the size of micelles in the polymerization solution correlates with the inner diameter of the nanotubes formed.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Eli Sutter, Peter Sutter
Summary: The integration of dissimilar materials into heterostructures is a main focus in modern materials science and technology. By combining 1D nanowires and 2D plates, mixed-dimensional heterostructures can be created with varying composition and dimensionality, resulting in larger contrast in electronic structures. Previous methods required multi-step growth processes, but this study demonstrates a single-step growth process using differences in precursor incorporation rates to synthesize mixed-dimensional heterostructures. This new approach opens up possibilities for complex heteroarchitectures.
Article
Electrochemistry
Yanis Levieux-Souid, Ananya Sathanikan, Francois Orange, Frederic Guittard, Thierry Darmanin
Summary: A soft electropolymerization approach was used to prepare highly ordered porous surface structures with benzotrithiophene-based monomers, leading to unique results with aromatic groups forming densely packed large open spheres. The porous surfaces hold potential for various applications such as water-harvesting systems, oil adsorbents, sensors, and drug delivery in the future.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Physical
Katarzyna Skibinska, Karolina Kolczyk-Siedlecka, Dawid Kutyla, Marta Gajewska, Piotr Zabinski
Summary: Copper and cobalt-iron 1D nanocones were successfully obtained using AAO templates through electrodeposition method. The Co-Fe nanostructures exhibited homogeneous pore distribution and were characterized for their electrocatalytic activity in 1 M NaOH solution. These materials can potentially serve as catalysts in water-splitting reaction, showing promising results when compared with bulk materials.
Review
Materials Science, Multidisciplinary
Hossein Anabestani, Rassel Shazzad, Md Fahim Al Fattah, Joel Therrien, Dayan Ban
Summary: GaAsSb nanowires are important ternary III-V nanowires with the potential to form one-dimensional heterojunction structures, making them promising candidates for fabricating novel electronic and optoelectronic devices. Their unique properties and high carrier mobility further contribute to their applications in electronic and optoelectronic devices.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Jianping Chen, Bin Liu, Hang Cai, Shude Liu, Yusuke Yamauchi, Seong Chan Jun
Summary: This study develops a covalently interlayer-confined organic-inorganic hybrid for improving the reaction kinetics of supercapacitors. The covalent assembly facilitates cross-layer electron transfer, increases active sites, and enhances the specific capacitance and rate capability of the hybrid material.
Review
Chemistry, Multidisciplinary
Xiaomin Xu, Ziru Lou, Simin Cheng, Philip C. Y. Chow, Norbert Koch, Hui-Ming Cheng
Summary: Van der Waals organic/inorganic heterostructures in the 2D limit show extensive structural tunability and have great potential in advancing the development of artificial solids with tailored functionalities. Recent breakthroughs in various types of 2D organic materials have enriched the design possibilities, making them applicable in advanced devices for transistors, optoelectronics, neuromorphic, and other multifunctional applications.
Article
Chemistry, Multidisciplinary
Jaime del Moral, Laura Montes, Victor Joaquin Rico-Gavira, Carmen Lopez-Santos, Stefan Jacob, Manuel Oliva-Ramirez, Jorge Gil-Rostra, Armaghan Fakhfouri, Shilpi Pandey, Miguel Gonzalez del Val, Julio Mora, Paloma Garcia-Gallego, Pablo Francisco Ibanez-Ibanez, Miguel Angel Rodriguez-Valverde, Andreas Winkler, Ana Borras, Agustin Rodriguez Gonzalez-Elipe
Summary: The use of acoustic waves for de-icing and anti-icing purposes shows promising potential, as it provides a synergistic effect when combined with surface modifications. Experiments conducted in laboratory and icing wind tunnel settings demonstrate the real-time monitoring capabilities of acoustic wave devices in icing processes.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Jorge Gil-Rostra, Javier Castillo-Seoane, Qian Guo, Ana Belen Jorge Sobrido, Agustin R. Gonzalez-Elipe, Ana Borras
Summary: This work proposes a new architecture of photoelectrodes consisting of supported multishell nanotubes fabricated by a soft-template approach. The obtained NT electrodes have a large electrochemically active surface and outperform the efficiency of equivalent planar-layered electrodes by more than one order of magnitude. The characteristics of the WO3/BiVO4 Schottky barrier heterojunction control the NT electrode efficiency, which depends on the BiVO4 outer layer thickness and the incorporation of the CoPi electrocatalyst, as demonstrated by thorough electrochemical analysis.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Gerardo Asensio, Ana M. Hernandez-Arriaga, Marcela Martin-del-Campo, M. Auxiliadora Prieto, Agustin R. Gonzalez-Elipe, Luis Rojo, Blanca Vazquez-Lasa
Summary: The accumulation of bacteria over implant surfaces is the main cause of failure, and the development of antimicrobial surfaces is crucial. Additionally, the durability and mechanical performance of implants are determined by their osseointegration capacity and infection prevention. Therefore, bioactive surfaces are being researched to improve implant osseointegration and infection prophylaxis.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
A. M. Alcaide, G. Regodon, F. J. Ferrer, V Rico, R. Alvarez, T. C. Rojas, A. R. Gonzalez-Elipe, A. Palmero
Summary: The formation of monoclinic VO2 crystal domains at low temperatures in nanocolumnar vanadium/oxygen thin films deposited via magnetron sputtering is analyzed. The synthesis involved depositing amorphous nanocolumnar VO1.9 thin films at room temperature and annealing them at temperatures between 250 - 330 ? in an oxygen atmosphere. The nanocolumnar structures exhibited a thermochromic transition at 47 ? (for annealing at 270 ?) and 58 ? (for annealing at 280 and 290 ?), resulting in a significant drop in optical transmittance in the infrared region.
Article
Chemistry, Multidisciplinary
Paula Navascues, Juan Garrido-Garcia, Jose Cotrino, Agustin R. Gonzalez-Elipe, Ana Gomez-Ramirez
Summary: This study investigates the synthesis of ammonia using plasma-catalysis and examines the role of various catalyst materials. The results show that while ruthenium particles have some catalytic activity under certain conditions, they do not significantly improve the yield and energy efficiency of ammonia synthesis. The ferroelectric material and the alumina coating play important roles in regulating discharge and cooling the plasma, respectively.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Materials Science, Multidisciplinary
Rafael Alvarez, Guillermo Regodon, Hiedra Acosta-Rivera, Victor Rico, German Alcala, Agustin R. Gonzalez-Elipe, Alberto Palmero
Summary: This paper studied the morphology and void connectivity of thin films grown by magnetron sputtering deposition at oblique geometries. A well-tested thin film growth model was used, along with experimental data, to assess the features of these layers. The film morphology and pore topology varied significantly with the growth conditions, which were linked to the different collisional transport of sputtered species in the plasma gas. Four different film morphologies were identified, and their porous network characteristics were described, explaining their potential applications in electrochromic sensors or infiltration with nanoparticles.
Article
Materials Science, Multidisciplinary
Stefan Jacob, Shilpi Pandey, Jaime Del Moral, Atefeh Karimzadeh, Jorge Gil-Rostra, Agustin R. Gonzalez-Elipe, Ana Borras, Andreas Winkler
Summary: This study successfully demonstrates the de-icing functionality of large areas covered with thick layers of glaze ice using nanoscale activation by surface acoustic waves. The method shows potential for practical applications in various industries.
ADVANCED MATERIALS TECHNOLOGIES
(2023)
Article
Nanoscience & Nanotechnology
Felix Carrascoso, Hao Li, Jose M. Obrero-Perez, Francisco J. Aparicio, Ana Borras, Joshua O. Island, Angel Barranco, Andres Castellanos-Gomez
Summary: By using an adamantane plasma polymer pinning layer, we achieve unprecedented crystal strains of 2.8% in monolayer molybdenum disulfide. The strain gauge factors for the A and B excitons of monolayer MoS2 are reported as -99.5 meV/% and -63.5 meV/%, respectively, with a 50 nm adamantane capping layer. Photoluminescence and Raman measurements on the same samples confirm these results. Overall, our study demonstrates that adamantane polymer is an exceptional capping layer for transferring substrate-induced strain to a 2D layer and achieving higher levels of crystal strain.
NPJ 2D MATERIALS AND APPLICATIONS
(2023)
Article
Materials Science, Multidisciplinary
V. Rico, G. F. Regodon, A. Garcia-Valenzuela, A. M. Alcaide, M. Oliva-Ramirez, T. C. Rojas, R. Alvarez, F. J. Palomares, A. Palmero, A. R. Gonzalez-Elipe
Summary: In this study, a novel methodology of plasma-assisted thin film structuration was proposed by combining piezoelectric AWs and plasmas during the growth of a thin film. SiO2 and SiOx (x<2) thin films were deposited by magnetron sputtering at oblique angles (MS-OAD) on an electro-acoustically excited LiNbO3 piezoelectric substrate under resonant conditions. The resulting films exhibited 2D patterned microstructure with submillimeter size intermingled zones, which replicated the distribution of polarization potential on the AW activated substrate immersed in the plasma. The main mechanism responsible for the appearance of domains with different morphology and chemical composition was found to be the focused impingement of Ar+ plasma ions on certain regions of the substrate. The discussed the general character of this patterning process, the underlying physics, and its possibilities to tailor the composition and microstructure of dielectric thin film materials.
Article
Chemistry, Multidisciplinary
Manuel Romero, Juan Ramon Sanchez-Valencia, Gabriel Lozano, Hernan Miguez
Summary: This work investigates the influence of the optical environment on the radiative decay rate of rare-earth transitions in luminescent nanoparticles forming a thin film, both theoretically and experimentally. By using finite-difference time-domain simulations and experiments, we propose modifications to existing analytical models for calculating the radiative decay rate and successfully achieve gradual and controllable alteration of the effective refractive index in luminescent films. Our research provides valuable insights for the rational tuning of the spontaneous decay rate and photoluminescence quantum yield in luminescent nanoparticle ensembles.
Article
Chemistry, Multidisciplinary
Laetitia Bardet, Herve Roussel, Stefano Saroglia, Masoud Akbari, David Munoz-Rojas, Carmen Jimenez, Aurore Denneulin, Daniel Bellet
Summary: The thermal instability of silver nanowires leads to increased electrical resistance in AgNW networks. Understanding the relationship between structural and electrical properties of AgNW networks is crucial for their integration as transparent electrodes in flexible optoelectronics. In situ X-ray diffraction measurements were used to study the crystallographic evolution of Ag-specific Bragg peaks during thermal ramping, revealing differences in thermal and structural transitions between bare and SnO2-coated AgNW networks.
Article
Chemistry, Multidisciplinary
Nathalia Cancino-Fuentes, Arnau Manasanch, Joana Covelo, Alex Suarez-Perez, Enrique Fernandez, Stratis Matsoukis, Christoph Guger, Xavi Illa, Anton Guimera-Brunet, Maria V. Sanchez-Vives
Summary: This study provides a comprehensive characterization of graphene-based solution-gated field-effect transistors (gSGFETs) for brain recordings, highlighting their potential clinical applications.
Article
Chemistry, Multidisciplinary
Sikandar Aftab, Hailiang Liu, Dhanasekaran Vikraman, Sajjad Hussain, Jungwon Kang, Abdullah A. Al-Kahtani
Summary: This study examines the effects of hybrid nanoparticles made of NiO@rGO and NiO@CNT on the active layers of polymer solar cells and X-ray photodetectors. The findings show that these hybrid nanoparticles can enhance the charge carrier capacities and exciton dissociation properties of the active layers. Among the tested configurations, the NiO@CNT device demonstrates superior performance in converting sunlight into electricity, and achieves the best sensitivity for X-ray detection.
Article
Chemistry, Multidisciplinary
Hyo Jung Shin, Seung Gyu Choi, Fengrui Qu, Min-Hee Yi, Choong-Hyun Lee, Sang Ryong Kim, Hyeong-Geug Kim, Jaewon Beom, Yoonyoung Yi, Do Kyung Kim, Eun-Hye Joe, Hee-Jung Song, Yonghyun Kim, Dong Woon Kim
Summary: This study investigates the role of SOX9 in reactive astrocytes following ischemic brain damage using a PLGA nanoparticle plasmid delivery system. The results demonstrate that PLGA nanoparticles can reduce ischemia-induced neurological deficits and infarct volume, providing a potential opportunity for stroke treatment.
Article
Chemistry, Multidisciplinary
Anurag Chaudhury, Koushik Debnath, Nikhil R. Jana, Jaydeep K. Basu
Summary: The study investigates the interaction between nanoparticles and cell membranes, and identifies key parameters, including charge, crowding, and membrane fluidity, that determine the adsorbed concentration and unbinding transition of nanoparticles.
Article
Chemistry, Multidisciplinary
Sina Sadeghi, Fazel Bateni, Taekhoon Kim, Dae Yong Son, Jeffrey A. Bennett, Negin Orouji, Venkat S. Punati, Christine Stark, Teagan D. Cerra, Rami Awad, Fernando Delgado-Licona, Jinge Xu, Nikolai Mukhin, Hannah Dickerson, Kristofer G. Reyes, Milad Abolhasani
Summary: In this study, an autonomous approach for the development of lead-free metal halide perovskite nanocrystals is presented, which integrates a modular microfluidic platform with machine learning-assisted synthesis modeling. This approach enables rapid and optimized synthesis of copper-based lead-free nanocrystals.
Article
Chemistry, Multidisciplinary
Zahir Abbas, Nissar Hussain, Surender Kumar, Shaikh M. Mobin
Summary: The rational construction of free-standing and flexible electrodes for electrochemical energy storage devices is an emerging research focus. In this study, a redox-active metal-organic framework (MOF) was prepared on carbon nanofibers using an in situ approach, resulting in a flexible electrode with high redox-active behavior and unique properties such as high flexibility and lightweight. The prepared electrode showed excellent cyclic retention and rate capability in supercapacitor applications. Additionally, it could be used as a freestanding electrode in flexible devices at different bending angles.
Article
Chemistry, Multidisciplinary
Lishan Zhang, Xiaoting Zhang, Hui Ran, Ze Chen, Yicheng Ye, Jiamiao Jiang, Ziwei Hu, Miral Azechi, Fei Peng, Hao Tian, Zhili Xu, Yingfeng Tu
Summary: Photodynamic therapy (PDT) is a promising local treatment modality in cancer therapy, but its therapeutic efficacy is restricted by ineffective delivery of photosensitizers and tumor hypoxia. In this study, a phototactic Chlorella-based near-infrared (NIR) driven green affording-oxygen microrobot system was developed for enhanced PDT. The system exhibited desirable phototaxis and continuous oxygen generation, leading to the inhibition of tumor growth in mice. This study demonstrates the potential of using a light-driven green affording-oxygen microrobot to enhance photodynamic therapy.
Article
Chemistry, Multidisciplinary
Yujin Li, Jing Xu, Xinqi Luo, Futing Wang, Zhong Dong, Ke-Jing Huang, Chengjie Hu, Mengyi Hou, Ren Cai
Summary: In this study, hollow heterostructured materials were constructed using an innovative template-engaged method as cathodes for zinc-ion batteries. The materials exhibited fast Zn2+ transport channels, improved electrical conductivity, and controlled volume expansion during cycling. The designed structure allowed for an admirable reversible capacity and high coulombic efficiency.
Article
Chemistry, Multidisciplinary
Paritosh Mahato, Shashi Shekhar, Rahul Yadav, Saptarshi Mukherjee
Summary: This study comprehensively elucidates the role of the core and electrostatic surface of metal nanoclusters in catalytic reduction reactions. The electrostatic surface dramatically modulates the reactivity of metal nanoclusters.
Article
Chemistry, Multidisciplinary
Pei Liu, Mengdi Liang, Zhengwei Liu, Haiyu Long, Han Cheng, Jiahe Su, Zhongbiao Tan, Xuewen He, Min Sun, Xiangqian Li, Shuai He
Summary: This study demonstrates a simple and environmentally-friendly method for the synthesis of zinc oxide nanozymes (ZnO NZs) using wasted hop extract (WHE). The WHE-ZnO NZs exhibit exceptional peroxidase-like activity and serve as effective catalysts for the oxidation of 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2). In addition, a straightforward colorimetric technique for detecting both H2O2 and glucose was developed using the WHE-ZnO NZs as peroxidase-like catalysts.
Article
Chemistry, Multidisciplinary
Hyunkyu Oh, Young Jun Lee, Eun Ji Kim, Jinseok Park, Hee-Eun Kim, Hyunsoo Lee, Hyunjoo Lee, Bumjoon J. Kim
Summary: Mesoporous carbon particles have unique structural properties that make them suitable as support materials for catalytic applications. This study investigates the impact of channel nanostructures on the catalytic activity of porous carbon particles (PCPs) by fabricating PCPs with controlled channel exposure on the carbon surface. The results show that PCPs with highly open channel nanostructures exhibit significantly higher catalytic activity compared to those with closed channel nanostructures.
Article
Chemistry, Multidisciplinary
Yunjie Lu, Zhaohui Li, Zewei Li, Shihao Zhou, Ning Zhang, Jianming Zhang, Lu Zong
Summary: A tough, long-lasting adhesive and highly conductive nanocomposite hydrogel (PACPH) was fabricated via the synergy of interfacial entanglement and adhesion group densification. PACPH possesses excellent mechanical properties, interfacial adhesion strength, and conductivity, making it a promising material for long-term monitoring of human activities and electrocardiogram signals.
Article
Chemistry, Multidisciplinary
Zichao Wei, Audrey Vandergriff, Chung-Hao Liu, Maham Liaqat, Mu-Ping Nieh, Yu Lei, Jie He
Summary: We have developed a simple method to prepare polymer-grafted plasmonic metal nanoparticles with pH-responsive surface-enhanced Raman scattering. By using pH-responsive polymers as ligands, the aggregation of nanoparticles can be controlled, leading to enhanced SERS. The pH-responsive polymer-grafted nanoparticles show high reproducibility and sensitivity in solution, providing a novel approach for SERS without the need for sample pre-concentration.
Article
Chemistry, Multidisciplinary
Melis Ozge Alas Colak, Ahmet Gungor, Merve Buldu Akturk, Emre Erdem, Rukan Genc
Summary: This research investigates the effect of functionalizing carbon dots with hydroxyl polymers on their performance as electrode materials in a supercapacitor. The results show that the functionalized carbon dots exhibit excellent electrochemical performance and improved stability.