Shape-Directed Binary Assembly of Anisotropic Nanoplates: A Nanocrystal Puzzle with Shape-Complementary Building Blocks

We present the binary self-assembly of two anisotropic nanoplate building blocks mediated by shape complementarity. We use rhombic GdF3 and tripodal Gd2O3 nanoplates as building blocks in which the size and shape are designed to be optimal for complementary organization. A liquid interfacial assembly technique allows the formation of self-assembled binary superlattices from two anisotropic nanoplates over a micrometer length scale. Shape-directed self-assembly guides the position of each anisotropic nanoplate in the binary superlattices, allowing for long-range orientational and positional order of each building block The design of shape complementary anisotropic building blocks offers the possibility to self-assemble binary superlattices with predictable and designable structures.