4.7 Article

Effective improvement of sensing performance of amperometric NO2 sensor by Ag-modified nano-structured CuO sensing electrode

期刊

SENSORS AND ACTUATORS B-CHEMICAL
卷 207, 期 -, 页码 791-800

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2014.10.125

关键词

NO2 sensor; La10Si5AlO26.5; Amperometric-type; Impregnating method; CuO-Ag

资金

  1. Natural Science Foundation of China [51272067, 51472073, 51201058]
  2. Iron-steel United Foundation of Hebei Province of China [E2012209018, E2011209036]

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An amperometric-type NO2 gas sensor using La10Si5AlO26.5 (LSAO) with the configuration of dense electrolyte porous electrolyte, Ag-modified nano-structured CuO sensing electrode was investigated. The composition and microstructure of the sensor sample were characterized by SEM and XRD and the performance of the sensor was examined. The prepared Ag-modified nano-structured CuO particles sensing electrode by impregnation technique are homogeneously dispersed in LSAO porous backbone. The sensor displays good response to NO2 and the response currents are almost linear to NO2 concentrations in the range of 0-500 ppm at 550-700 degrees C. Ag addition to the CuO sensing electrode can remarkably increase sensor sensitivity, showing that the performance of the sensor is effectively improved by introducing Ag. The best performance is observed at molar ratio of 1:0.5 for CuO: Ag. The cross-sensitivities of the sensor to co-existant gases (H-2, CH4, CO2, NH3 and toluene) are rather small. (C) 2014 Elsevier B.V. All rights reserved.

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