4.3 Article

ELECTRODEPOSITION OF POLYPYRROLE/MnO2 NANOCOMPOSITE ON GRAPHITE FELT AS FREE-STANDING ELECTRODE FOR SUPERCAPACITORS

期刊

NANO
卷 8, 期 2, 页码 -

出版社

WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793292013500203

关键词

Polypyrrole; manganese dioxide; graphite felt; electrochemical properties

资金

  1. Functional Polymer Materials Engineering Technology Research Center of Fujian province [2010H2005]
  2. Important Item of PA6/Kevlar Fiber Composite and Research of Key Technology [JK2011004]

向作者/读者索取更多资源

Polypyrrole/manganese dioxide nanocomposite was deposited on graphite felt (GF) via electrodeposition to fabricate polypyrrole/manganese dioxide/graphite felt (PYMG), which can be used as novel free-standing electrode for supercapacitors. The microstructure and morphology of the as-prepared samples were characterized by Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Cyclic voltammogram (CV), chronopotentiometry (CP) and electrochemical impedance spectroscopy (EIS) techniques were employed to investigate the electrochemical performance of the composites. The PYMG electrode displayed specific capacitance as high as 596.3 Fg(-1) at the current density of 0.5 Ag-1, which is much higher than that of polypyrrole/manganese dioxide (PPy/MnO2) composite reported previously. The high specific capacitance of PYMG may be attributed to the fact that the porous GF is a good conductive matrix for the dispersion of PPy/MnO2 composite and it can facilitate easy access of electrolytes to the electrode, which results in enhancement of the electrochemical performance of the composite. Furthermore, the PYMG composite exhibited enhanced specific capacitance compared to MnO2/GF (MGF) and PPy/GF, which may be ascribed to the synergistic effect of PPy and MnO2.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.3
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据