期刊
MOLECULES
卷 19, 期 1, 页码 352-366出版社
MDPI
DOI: 10.3390/molecules19010352
关键词
pyrene; excimers; fullerene; fluorescence; energy transfer; photovoltaics
资金
- CONACYT [128788]
A series of pyrene-fullerene C-60 dyads bearing pyrene units (PyFC12, PyFPy, Py2FC12 and PyFN) were synthesized and characterized. Their optical properties were studied by absorption and fluorescence spectroscopies. Dyads were designed in this way because the pyrene moeities act as light-harvesting molecules and are able to produce monomer (PyFC12) or excimer emission (PyFPy, Py2FC12 and PyFN). The fluorescence spectra of the dyads exhibited a significant decrease in the amount of pyrene monomer and excimer emission, without the appearance of a new emission band due to fullerene C-60. The pyrene fluorescence quenching was found to be almost quantitative, ranging between 96%-99% depending on the construct, which is an indication that energy transfer occurred from one of the excited pyrene species to the fullerene C-60.
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