4.7 Article

Fate of hazardous elements in agricultural soils surrounding a coal power plant complex from Santa Catarina (Brazil)

期刊

SCIENCE OF THE TOTAL ENVIRONMENT
卷 508, 期 -, 页码 374-382

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.scitotenv.2014.12.015

关键词

Agricultural soil; Element contamination; Coal power plant; Hotspot identification; Spatial interpolation; Principal Component Analysis

资金

  1. SUDOE Interreg IV B Programme through the ORQUE SUDOE Project [SOE3/P2/F591/5]
  2. Basque Government through Consolidated Research Group Project [IT-742-13]
  3. UPV/EHU

向作者/读者索取更多资源

Hazard element contamination coming from coal power plants is something obvious, but when this contamination is accompanied by other contamination sources, such as, urban, coal mining and farming activities the study gets complicated. This is the case of an area comprised in the southern part of Santa Catarina state (Brazil) with the largest private power plant generator. After the elemental analysis of 41 agricultural soils collected in an extensive area around the thermoelectric (from 0 to 47 km), the high presence of As, Co, Cr, Cu, Fe, Mn, Mo, Pb, Sb, Sn, Tl, V and Zn was found in some specific areas around the power plant Nevertheless, as the NWAC (Normalized-and-Weighted Average Concentration) confirmed, only soils from one site were classified as of very high concern due to the presence of potential toxic elements. This site was located within the sedimentation basin of the power plant. The spatial distribution obtained by kriging in combination with the analysis of the data by Principal Component Analysis (PCA) revealed three important hotspots in the area according to soil uses and geographic localization: the thermoelectric, its area of influence due to volatile compound deposition, and the area comprised between two urban areas. Farming practice turn out to be an important factor too for the quantity of hazard element stored in soils. (C) 2014 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Environmental Sciences

Application of Pb-Fe spinel-activated carbon for phenol removal from aqueous solutions: fixed-bed adsorption studies

Esmaeil Allahkarami, Abolfazl Dehghan Monfared, Luis Felipe Oliveira Silva, Guilherme Luiz Dotto

Summary: In this study, fixed-bed experiments were conducted using a novel Pb-Fe spinel-activated carbon adsorbent for phenol uptake from water. The adsorbent was characterized and compared to pristine activated carbon. The results showed that the Pb-Fe spinel-activated carbon composite had a higher adsorption capacity and was suitable for fixed-bed adsorption of phenol.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Spectroscopy

Characterization of olivines and their metallic composition: Raman spectroscopy could provide an accurate solution for the active and future Mars missions

Imanol Torre-Fdez, Cristina Garcia-Florentino, Jennifer Huidobro, Leire Coloma, Patricia Ruiz-Galende, Julene Aramendia, Kepa Castro, Gorka Arana, Juan Manuel Madariaga

Summary: The presence and geochemical composition of olivine on Mars are important for studying the planet. Raman spectrometers, used in Mars 2020 and future missions, provide new possibilities to determine the Mg/Fe ratios in olivine-bearing rocks. Olivine's presence indicates past volcanic activity on Mars, and its forsterite/fayalite ratio can reveal information about the origin and evolution of the parent magma. This study proposes a new calibration model using Raman spectroscopy, greatly improving the accuracy and uncertainty associated with the forsterite/fayalite ratios compared to previous literature.

JOURNAL OF RAMAN SPECTROSCOPY (2023)

Article Green & Sustainable Science & Technology

Brazilian Coal Tailings Projects: Advanced Study of Sustainable Using FIB-SEM and HR-TEM

Marcos L. S. Oliveira, Diana Pinto, Maria Eliza Nagel-Hassemer, Leila Dal Moro, Giana de Vargas Mores, Brian William Bodah, Alcindo Neckel

Summary: The objective of this study is to assess particles containing rare-earth elements (REEs) in abandoned deposits of Brazilian fine coal tailings (BFCTs) and identify extraction methods. The BFCT areas were analyzed using X-ray Diffraction, Raman Spectroscopy, focused ion beam coupled with scanning electron microscopy, and high-resolution transmission electron microscopy coupled with microanalysis. The results showed higher concentrations of REEs in smaller coal fines. These easily extractable deposits, located close to transportation routes, present an opportunity for secondary market utilization rather than discarding.

SUSTAINABILITY (2023)

Article Environmental Sciences

Air pollution in central European capital (Budapest) via self-made passive samplers and Sentinel-3B SYN satellite images

Alcindo Neckel, Marcos L. S. Oliveira, Laercio Stolfo Maculan, Brian William Bodah, Affonso Celso Goncalves Jr, Luis F. O. Silva

Summary: This study identifies the types of ultra-fine air pollutants present in the local atmosphere of Budapest using satellite images and physical sample collection. The results reveal the presence of ultra-fine particles containing elements harmful to human health. The study also highlights the importance of reducing pollutants for a better quality of life in the city.

URBAN CLIMATE (2023)

Article Archaeology

The Ychsma ceramic provenance from Armatambo, 1250 - 1532 CE (Lima Peru). A local or imported production?

Dante Pareja, Javier Inanez, Ayed Ben Amara, Luisa Diaz, Gorka Arana, Remy Chapoulie

Summary: The Ychsma society, developed in Lima, Peru between 900 and 1532 CE, was one of the most significant civilizations in the region. Despite being conquered by the Inca Empire around 1470 CE, the local elites in the Ychsma region maintained their position and control under Inca rule. The archaeological site of Armatambo played a crucial role as an administrative center and controlled a large part of the lower Rimac valley.

JOURNAL OF ARCHAEOLOGICAL SCIENCE-REPORTS (2023)

Article Chemistry, Physical

Highly furosemide uptake employing magnetic graphene oxide: DFT modeling combined to experimental approach

Guilherme Oliveira Vargas, Carlos Schnorr, Franciane Bastista Nunes, Theodoro da Rosa Salles, Mariana Zancan Tonel, Solange Binotto Fagan, Ivana Zanella da Silva, Luis F. O. Silva, Sergio Roberto Mortari, Guilherme Luiz Dotto, Cristiano Rodrigo Bohn Rhoden

Summary: This study reports the synthesis of magnetic graphene oxide (GO Fe3O4) with different amounts of iron nanoparticles for the adsorption of furosemide (FUR). The optimal adsorbent was found to be GO Fe3O4 1:1, with a removal percentage and adsorption capacity of 96.15% and 96.91 mg g-1, respectively, at pH 3.0 and 293.15 K. The process was influenced by initial concentration, adsorbent dosage, and pH, while the ionic strength had minimal effect on the performance of GO Fe3O4 1:1. Sips and PSO models were the best fit for the experimental data, indicating a heterogeneous surface. GO Fe3O4 1:1 exhibited high removal percentage even after several cycles of adsorption/desorption.

JOURNAL OF MOLECULAR LIQUIDS (2023)

Article Biochemistry & Molecular Biology

Adsorptive Features of Magnetic Activated Carbons Prepared by a One-Step Process towards Brilliant Blue Dye

Victoria X. X. Nascimento, Carlos Schnorr, Sabrina F. F. Luetke, Maria C. F. Da Silva, Fernando Machado Machado, Pascal S. S. Thue, Eder C. Lima, Julien Vieillard, Luis F. O. Silva, Guilherme L. L. Dotto

Summary: Water pollution by dyes is a major problem, and magnetic activated carbons show promise as alternatives. In this study, magnetic activated carbons were prepared and used for the removal of brilliant blue dye. The different proportions of the materials influenced the adsorption kinetics and equilibrium of the dye.

MOLECULES (2023)

Article Geography, Physical

The effect of low temperature on the Raman spectra of calcium-rich sulfates on Mars

Jennifer Huidobro, Julene Aramendia, Gorka Arana, Elisabeth M. Hausrath, Juan Manuel Madariaga

Summary: Raman spectra of gypsum, syngenite, and gorgeyite powders were analyzed at different temperatures. The main bands of the three sulfates shifted towards higher wavenumbers with decreasing temperature, indicating stronger bonds and higher energy. However, the behavior of -OH bands varied depending on the crystal structure acquired at different temperatures. The -OH bands of gypsum became narrower and sharper with decreasing temperature, indicating a more ordered crystalline structure.

ANNALS OF GLACIOLOGY (2023)

Editorial Material Green & Sustainable Science & Technology

Remote Sensing Studies Applied to the Use of Satellite Images in Global Scale

Luis F. O. Silva, Marcos L. S. Oliveira

SUSTAINABILITY (2023)

Review Geosciences, Multidisciplinary

Organic geochemistry of in situ thermal-based analyses on Mars: the importance and influence of minerals

Mark A. Sephton, Jonathan S. W. Tan, Jonathan S. Watson, Keyron Hickman-Lewis, Juan M. Madariaga

Summary: The search for organic biomarkers on Mars is a high-priority goal for past, present, and future missions. Thermal extraction is the most popular in situ analysis technique, but it faces challenges when analyzing mineral-organic mixtures. Potential mitigations are suggested for future experiments, which can be used both on Mars and on returned samples on Earth.

JOURNAL OF THE GEOLOGICAL SOCIETY (2023)

Article Biochemistry & Molecular Biology

Study of Micro-Samples from the Open-Air Rock Art Site of Cueva de la Vieja (Alpera, Albacete, Spain) for Assessing the Performance of a Desalination Treatment

Ilaria Costantini, Julene Aramendia, Nagore Prieto-Taboada, Gorka Arana, Juan Manuel Madariaga, Juan Francisco Ruiz

Summary: In this study, micro-samples from a rock art site in Spain were analyzed to understand the conservation state of the painted panel and to confirm the efficacy of a desalination treatment. Various techniques were used for characterization, revealing the presence of dolomitic limestone, silicon aggregates, aluminosilicates, iron oxides, and sulfate compounds. The analysis also showed evidence of biological activity and the presence of calcium oxalates, which likely contribute to the preservation of the pictographs. The presence of carotenoid pigments and the intentional use of hematite for painting were also identified.

MOLECULES (2023)

Article Engineering, Environmental

Adsorptive properties of highly porous activated carbon from acai (Euterpe oleracea) towards the toxic herbicide atrazine

Rolando Ramirez, Diana Pinto, Jordana Georgin, Anelise H. P. de Oliveira, Dison S. P. Franco, Delmira Wolff, Elvis Carissimi, Mu. Naushad, Luis F. O. Siva, Eder C. Lima, Guilherme L. Dotto

Summary: The consumption of acai pulp (Euterpe oleracea) has increased significantly in recent years, resulting in the generation of large amounts of waste from the fruit stone. This study successfully converted the waste into activated carbon, which effectively removed the herbicide atrazine. The activated carbon showed good textural characteristics and demonstrated high efficiency and affinity for the target molecule.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Engineering, Environmental

Selective adsorption of gadolinium from real leachate using a natural bentonite clay

Guilherme L. Dotto, Julien Vieillard, Diana Pinto, Sabrina F. Luetke, Luis F. O. Silva, Glaydson S. dos Reis, Eder C. Lima, Dison S. P. Franco

Summary: This study investigated the recovery of Gd3+ from real leachate of phosphogypsum using natural bentonite clay. The adsorption study revealed that the clay has typical bentonite characteristics and can effectively adsorb Gd3+. The kinetics and thermodynamics of the adsorption process were analyzed, and it was found that the Langmuir model and Avrami fractional order model were suitable for describing the adsorption isotherms and kinetic data, respectively. The study also showed that citric acid was an efficient desorbing agent for Gd3+ from the bentonite, and the clay could selectively recover Gd3+ from the real leachate of phosphogypsum.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Environmental Sciences

Brilliant blue FCF dye adsorption using magnetic activated carbon from Sapelli wood sawdust

Victoria X. Nascimento, Diana Pinto, Sabrina F. Lutke, Maria C. F. da Silva, Fernando. M. Machado, Eder. C. Lima, Luis F. O. Silva, Guilherme L. Dotto

Summary: Sapelli wood sawdust-derived magnetic activated carbon (SWSMAC) was produced through single-step pyrolysis using KOH and NiCl2 as activating and magnetization agents. The obtained SWSMAC was a mesoporous material with good textural properties and exhibited ferromagnetic properties. It effectively adsorbed brilliant blue FCF dye through various interactions.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Environmental Sciences

Wood waste-based functionalized natural hydrochar for the effective removal of Ce(III) ions from aqueous solution

Glaydson S. dos Reis, Carlos E. Schnorr, Guilherme L. Dotto, Julien Vieillard, Matias S. Netto, Luis F. O. Silva, Irineu A. S. De Brum, Mikael Thyrel, Eder C. Lima, Ulla Lassi

Summary: This study investigated the adsorption and recovery of cerium (Ce(III)), a rare earth element, from an aqueous solution using a sustainable hydrochar made from wood waste. The hydrochar contained various surface functional groups, which significantly influenced its adsorption capacity. The pH of the solution strongly affected the Ce(III) removal, with the highest removal efficiency achieved at pH 6.0. The hydrochar exhibited high efficiency in Ce(III) adsorption, with a maximum adsorption capacity of 327.9 mg g(-1) at 298 K. The adsorption kinetics followed the general order model, while the equilibrium process fit the Liu isotherm model. The Ce(III) adsorption mechanism on the hydrochar involved electrostatic interactions and chelation between surface functional groups and Ce(III). The hydrochar also demonstrated excellent regeneration capacity using sulfuric acid as an eluent. This research presents a sustainable approach for developing an efficient adsorbent for Ce(III) removal with excellent physicochemical properties.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Environmental Sciences

Comparing nearshore and embayment scale assessments of submarine groundwater discharge: Significance of offshore groundwater discharge as a nutrient pathway

Toshimi Nakajima, Mao Kuragano, Makoto Yamada, Ryo Sugimoto

Summary: This study compared the contribution of submarine groundwater discharge (SGD) to river nutrient budgets at nearshore and embayment scales, and found that SGD-derived nutrients become more important at larger spatial scales.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Impact of NO2 emissions from household heating systems with wall-mounted gas stoves on indoor and ambient air quality in Chinese urban areas

Fan Liu, Lei Zhang, Chongyang Zhang, Ziguang Chen, Jingguang Li

Summary: NO2 emissions from wall-mounted gas stoves used for household heating have become a significant source of indoor pollution in Chinese urban areas. The high indoor concentration of NO2 poses potential health risks to residents. It is urgently necessary to establish relevant regulations and implement emission reduction technologies to reduce NO2 emissions from wall-mounted gas stoves.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Letter Environmental Sciences

Letter to the editor regarding Collard et al. (2023): Persistence and mobility (defined as organic-carbon partitioning) do not correlate to the detection of substances found in surface and groundwater: Criticism of the regulatory concept of persistent and mobile substances

Hans Peter H. Arp, Raoul Wolf, Sarah E. Hale, Sivani Baskaran, Juliane Gluege, Martin Scheringer, Xenia Trier, Ian T. Cousins, Harrie Timmer, Roberta Hofman-Caris, Anna Lennquist, Andre D. Bannink, Gerard J. Stroomberg, Rosa M. A. Sjerps, Rosa Montes, Rosario Rodil, Jose Benito Quintana, Daniel Zahn, Herve Gallard, Tobias Mohr, Ivo Schliebner, Michael Neumann

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Harnessing the composition of dissolved organic matter in lagoon sediment in association with rare earth elements using fluorescence and UV-visible absorption spectroscopy

Philomina Onyedikachi Peter, Binessi Edouard Ifon, Francois Nkinahamira, Kayode Hassan Lasisi, Jiangwei Li, Anyi Hu, Chang-Ping Yu

Summary: This study investigates the relationship between dissolved organic matter (DOM) and Rare Earth Elements (REEs) in sediments from Yundang Lagoon, China. The results show four distinct fluorescent components, with protein-like substances being the most prevalent. Additionally, the total fluorescence intensity and LREE concentrations exhibit a synchronized increase from Outer to Inner to Songbai Lake core sediments. The findings demonstrate a strong correlation between DOM content and pollution levels.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

An advanced global soil erodibility (K) assessment including the effects of saturated hydraulic conductivity

Surya Gupta, Pasquale Borrelli, Panos Panagos, Christine Alewell

Summary: The objective of this study is to incorporate soil hydraulic properties into the erodibility factor (K) of USLE-type models. By modifying and improving the existing equations for soil texture and permeability, the study successfully included information on saturated hydraulic conductivity (Ksat) into the calculation of K factor. Using the Random Forest machine learning algorithm, two independent K factor maps with different spatial resolutions were generated. The results show that the decrease in K factor values has a positive impact on the modeling of soil erosion rates.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Comparison of adsorption-extraction (AE) workflows for improved measurements of viral and bacterial nucleic acid in untreated wastewater

Jesmin Akter, Wendy J. M. Smith, Yawen Liu, Ilho Kim, Stuart L. Simpson, Phong Thai, Asja Korajkic, Warish Ahmed

Summary: The choice of workflow in wastewater surveillance has a significant impact on SARS-CoV-2 concentrations, while having minimal effects on HF183 and no effect on HAdV 40/41 concentrations. Certain components in the workflow can be interchangeable, but factors such as buffer type, chloroform, and homogenization speed can affect the recovery of viruses and bacteria.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Insights the dominant contribution of biomass burning to methanol-soluble PM2.5 bounded oxidation potential based on multilayer perceptron neural network analysis in Xi'an, China

Yu Luo, Xueting Yang, Diwei Wang, Hongmei Xu, Hongai Zhang, Shasha Huang, Qiyuan Wang, Ningning Zhang, Junji Cao, Zhenxing Shen

Summary: Atmospheric PM2.5, which can generate reactive oxygen species (ROS), is associated with cardiorespiratory morbidity and mortality. The study found that both the mass concentration of PM2.5 and the DTT activity were higher during the heating season than during the nonheating season. Combustion sources were the primary contributors to DTT activity during the heating season, while secondary formation dominated during the nonheating season. The study also revealed that biomass burning had the highest inherent oxidation potential among all sources investigated.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

A macroplastic vulnerability index for marine mammals, seabirds, and sea turtles in Hawai'i

Erin L. Murphy, Leah R. Gerber, Chelsea M. Rochman, Beth Polidoro

Summary: Plastic pollution has devastating consequences for marine organisms. This study uses a trait-based framework to develop a vulnerability index for marine mammals, seabirds, and sea turtles in Hawai'i. The index ranks 63 study species based on their vulnerability to macroplastic pollution, providing valuable information for species monitoring and management priorities.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Anthropic disturbances impact the soil microbial network structure and stability to a greater extent than natural disturbances in an arid ecosystem

Kenji Maurice, Amelia Bourceret, Sami Youssef, Stephane Boivin, Liam Laurent-Webb, Coraline Damasio, Hassan Boukcim, Marc-Andre Selosse, Marc Ducousso

Summary: Growing pressure from climate change and agricultural land use is destabilizing soil microbial community interactions. Little is known about microbial community resistance and adaptation to disturbances, hindering our understanding of recovery latency and implications for ecosystem functioning. This study found that anthropic disturbance and natural disturbance have different effects on the topology and stability of soil microbial networks.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Adsorption of metal ions by oceanic manganese nodule and deep-sea sediment: Behaviour, mechanism and evaluation

Yunhao Li, Yali Feng, Haoran Li, Yisong Yao, Chenglong Xu, Jinrong Ju, Ruiyu Ma, Haoyu Wang, Shiwei Jiang

Summary: Deep-sea mining poses a serious threat to marine ecosystems and human health by disturbing sediment and transmitting metal ions through the food chain. This study developed a new regenerative adsorption material, OMN@SA, which effectively removes metal ions. The adsorption mechanism and performance of the material for metal ion fixation were investigated.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Advanced oxidation process of valsartan by activated peroxymonosulfate: Chemical characterization and ecotoxicological effects of its byproducts

Antonio Medici, Margherita Lavorgna, Marina Isidori, Chiara Russo, Elena Orlo, Giovanni Luongo, Giovanni Di Fabio, Armando Zarrelli

Summary: Valsartan, a widely used antihypertensive drug, has been detected in high concentrations in surface waters due to its unchanged excretion and incomplete degradation in wastewater treatment plants. This study investigated the degradation of valsartan and identified 14 degradation byproducts. The acute and chronic toxicity of these byproducts were evaluated in key organisms in the freshwater trophic chain.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Photodegradation of typical pharmaceuticals changes toxicity to algae in estuarine water: A metabolomic insight

Jiang Lin, Lianbao Chi, Qing Yuan, Busu Li, Mingbao Feng

Summary: This study investigated the photodegradation behavior and product formation of two representative pharmaceuticals in simulated estuary water. The study found that the formed transformation products of these pharmaceuticals have potential toxicity on marine organisms, including oxidative stress and damage to cellular components.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Association of ambient air pollution and pregnancy rate among women undergoing assisted reproduction technology in Fujian, China: A retrospective cohort study

Hua Fang, Dongdong Jiang, Ye He, Siyi Wu, Yuehong Li, Ziqi Zhang, Haoting Chen, Zixin Zheng, Yan Sun, Wenxiang Wang

Summary: This study revealed that exposure to lower levels of air pollutants led to decreased pregnancy rates, with PM10, NO2, SO2, and CO emerging as the four most prominent pollutants. Individuals aged 35 and above exhibited heightened susceptibility to pollutants.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

The predictive machine learning model of a hydrated inverse vulcanized copolymer for effective mercury sequestration from wastewater

Ali Shaan Manzoor Ghumman, Rashid Shamsuddin, Amin Abbasi, Mohaira Ahmad, Yoshiaki Yoshida, Abdul Sami, Hamad Almohamadi

Summary: In this study, inverse vulcanized polysulfides (IVP) were synthesized by reacting molten sulfur with 4-vinyl benzyl chloride, and then functionalized using N-methyl D-glucamine (NMDG). The functionalized IVP showed a high mercury adsorption capacity and a machine learning model was developed to predict the amount of mercury removed. Furthermore, the functionalized IVP can be regenerated and reused, providing a sustainable and cost-effective adsorbent.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)

Article Environmental Sciences

Aluminium bioaccumulation in colon cancer, impinging on epithelial-mesenchymal-transition and cell death

Rita Bonfiglio, Renata Sisto, Stefano Casciardi, Valeria Palumbo, Maria Paola Scioli, Erica Giacobbi, Francesca Servadei, Gerry Melino, Alessandro Mauriello, Manuel Scimeca

Summary: This study investigated the presence of aluminum in human colon cancer samples and its potential association with biological processes involved in cancer progression. Aluminum was found in tumor areas of 24% of patients and was associated with epithelial to mesenchymal transition (EMT) and cell death. Additional analyses revealed higher tumor mutational burden and mutations in genes related to EMT and apoptosis in aluminum-positive colon cancers. Understanding the molecular mechanisms of aluminum toxicity may improve strategies for the management of colon cancer patients.

SCIENCE OF THE TOTAL ENVIRONMENT (2024)