期刊
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
卷 604, 期 1, 页码 41-51出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/15421406.2014.967653
关键词
azulenylpyridine; fluorescence; Azobenzene; photoisomerization
资金
- Romanian Ministry of Education, Research, Youth and Sports, through the UEFISCDI organism [279/7.10.2011, PN-II-ID-PCE-2011-3-0505]
Fluorescent properties and the photoisomerization behaviour of 4-azulenylpyridine-substituted azobenzenes were investigated. All studied compounds have shown fluorescent emission in solution, originating from excited singlet state S-2 -> S-0 of azulene moiety. The substitution of the azobenzene chromophore has affected the preservation of the fluorescence emission in thin films prepared in PMMA matrix. Correlation of absorption spectra with H-1-NMR spectroscopy revealed that for all compounds the E -> Z isomerization takes place upon exposure to UV light.
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