期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 190, 期 -, 页码 334-345出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2014.02.032
关键词
TAPO-5; Ti(III) sources; Ti(OP)(4) environments; Water retention; Isomorphous substitution mechanisms
类别
资金
- Spanish Ministry [MAT-2012-31127]
- CSIC for a JAE-predoc fellowship
This work focuses on the synthesis and characterization of a conceptually innovative series of TAPO materials, particularly centered in the AFI-structured TAPO-5. Unlike the conventional TAPOs, the socalled Ti(III)APO-5 are prepared by using Ti(III) sources. This strategy aims to avoid the presence of both Ti-O-Al and Ti-O-Ti bonds in TAPOs, undesired for catalytic purposes. The thermodynamic. stability of this oxidation state of Ti in water and in the presence of air is low, but the preparation of the gel and the filling of the autoclaves under N-2 atmosphere allowed Ti to maintain its 3+ oxidation state in a considerable proportion in the hydrothermally-crystallized solids. The materials were characterized by powder XRD, ICP chemical analysis, SEM, DR-UV-visible spectroscopy, TGA and P-31 and Al-27 MAS NMR. DR-UV-visible spectroscopy certified the presence of Ti(III) in both tetrahedral and octahedral environments in the as-made samples before being exposed to air, whereas P-31 MAS NMR indicated the vicinity of Ti in the second coordination sphere of P in the already oxidized sample. Although once dried and calcined in air Ti(III) is entirely oxidized to Ti(IV), Ti(III)APO-5 materials present key singularities against conventional TAPO-5. Thus, apart from the presence of Ti(OP)(4) environments, the charge transfer transition detected by DR-UV-vis appears at lower wavelength, whereas both TGA and Al-27 NMR indicates a peculiar hydration of the as-prepared samples, which is unprecedented in conventional TAPO-5. Based on these characterization features, the possible nature of the Ti centers generated by this synthesis approach is discussed. (C) 2014 Elsevier Inc. All rights reserved.
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