期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 172, 期 -, 页码 131-135出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2013.01.018
关键词
Phosphoric acid; Phenol-based activated carbon; Electric double layer capacitor; Electrochemical properties
类别
资金
- IT R&D program of MKE/KEIT [KI002177-2013-05]
To improve the electrochemical performance of an activated carbon (AC)-based electric double-layer capacitor (EDLC), the AC surface, which is used as an electrode, was modified using different concentrations of phosphoric acid. The effects of the treatment on the surface and electrochemical properties of the AC electrodes were investigated. The specific capacitance increased from 256 F/g for an untreated sample to 452 F/g for a sample treated with a 2 M solution at a scan rate of 5 mV/s. This increase can be attributed to an increase in the mesopore volume caused by the etching effect of the reaction between the carbon surfaces and phosphoric acid. In addition, oxygen functional groups, which were introduced by the treatment, improved the electrochemical properties of the resulting AC-based electrode. Therefore, simultaneous etching and oxygen introduction with phosphoric acid can easily bind oxygen functional groups (particularly C=O) onto the surface of an AC electrode. This method is effective at preparing AC for use in an EDLC with improved electrochemical properties. (C) 2013 Elsevier Inc. All rights reserved.
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