期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 151, 期 -, 页码 397-402出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2011.10.003
关键词
Manganese oxide; Birnessite; Formaldehyde; Complete oxidation
类别
资金
- National Natural Science Foundation of China [20871118, 21007076]
- Chinese Academy of Sciences (CAS) [KSCX2-YW-G-059]
- National Basic Research Program of China [2010CB934103]
Birnessite - type manganese oxides with very high surface areas (up to 154 m(2)/g) were successfully prepared using a microemulsion process. The morphology, surface area, pore size, and the surface reducibility of these materials were readily tailored via the synthesis temperature. The physiochemical properties of the manganese oxides were characterized by means of XRD, TEM, SEM, BET and H-2-TPR techniques. These materials were also catalytically tested in HCHO oxidation, showing significantly high catalytic activity. It was found that the differences in catalytic performance of these materials were jointly attributed to the effects of the morphology, surface area and surface reducibility. The highly porous feature of the catalyst with nanospheres could allow HCHO molecules to easily diffuse onto catalytically active sites, which endows the nanospheres with high catalytic activity. The higher the surface area, the higher its catalytic activity. A higher surface reducibility offered a lower temperature of HCHO oxidation. The most active manganese catalyst (BSW-120) showed a 100% HCHO conversion at 100 degrees C. (c) 2011 Elsevier Inc. All rights reserved.
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