期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 124, 期 1-3, 页码 204-209出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2009.05.011
关键词
ECT; Hydrothermal stability; Mesoporous; Fluoride; Polymethylsiloxane
类别
资金
- Morning Light Plan of Shanghai Education Development Foundation [2007CG040]
- Shanghai Natural Science Foundation [08ZR1406100]
- National Basic Research of China [2007CB613301, 2004CB719500]
- National Nature Science Foundation of China [20773039]
- Research Fund for the Doctoral Program of Higher Education [20070251006]
- Ministry of Science and Technology of China [2006AA06Z379, 2007AA05Z303, 2006DFA52710]
Mesoporous silica with thick pore wall (designated ECT) was synthesized in the presence of fluoride anions by using nonionic organosilicon surfactant (K903) as template. According to the results from XRD patterns and N-2 adsorption-desorption analysis, the addition of fluoride has a strong effect on the pore diameter and pore wall thickness of the ECT samples. Si-29 MAS NMR indicates that the degree of silicate condensation is greatly enhanced by adding fluoride ions. The hydrothermal stability of the mesoporous silica (ECT) synthesized in the presence of fluoride was found to be greatly improved compared to that of the sample without addition of fluoride ions. When F/Si = 0.045, the mesostructure of the sample could still remain after refluxed in boiling water even for 20 days. The ultra hydrothermal stability could be attributed to its thick pore wall, less defects in the silica framework and high degree of polymerization of silicate. Moreover, results from SEM reveal that the addition of fluoride anions also has great effect on the morphology structure of ECT sample. (C) 2009 Elsevier Inc. All rights reserved.
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