期刊
MICROCHIMICA ACTA
卷 181, 期 5-6, 页码 671-677出版社
SPRINGER WIEN
DOI: 10.1007/s00604-014-1172-2
关键词
Carbon dots; Chemiluminescence; Dopamine; Cerium
We show that the very weak chemiluminescence (CL) of the Ce(IV)-thiosulfate system is enhanced by a factor of similar to 150 in the presence of fluorescent carbon dots (C-dots). The C-dots were prepared by a solvothermal method and characterized by fluorescence spectra and transmission electron microscopy. Possible mechanisms that lead to the effect were elucidated by recording fluorescence and CL spectra. It is found that dopamine at even nanomolar levels exerts a diminishing effect on the enhancement of CL. This was exploited to design a method for the determination of dopamine in the concentration range from 2.5 nM to 20 mu M, with a limit of detection (at 3 s) of 1.0 nM. Dopamine was determined by this method in spiked human plasma samples with satisfactory results.
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